Synthesis and Characterization of Organometallic Cyanides and Phthalocyanines

pi-arene complexes of octaalkoxyphthalocyanines and metallophthalocyanines were prepared by reaction of soluble phthalocyanine (H2PcOR) and metallophthalocyanine (M(PcOR)) ligands with Cp*Ru(NCMe)3 +. The molecular structure of {Cp*Ru[eta6-Ni(PcOBu)]}PF 6 consists of a dimer of two cofacially stacked {Cp*Ru[eta 6-Ni(PcOBu)]}+ units. In [Cp*Ru(eta6-H 2PcOEt)]PF6 the two NH protons exhibit differences in reactivity, and the N4H2 pocket can be metallated.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2015

Author dc:creator

• Contakes, Stephen Myron

Contributors dc:contributor

• Rauchfuss, Thomas B.

• Chemistry, Inorganic

Language dc:language

eng

Identifier

(MiAaPQ)AAI3023036

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/84034