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University of Illinois at Urbana-Champaign
Challenging Theories in Surface Science: Models of Active Sites and Carbon Monoxide Surface Binding
Abstract
dc:descriptionThe reactions of 1,1,1,5,5,5-hexafluoro-2,4-pentanedione on O/Pt(110) have been studied with temperature-programmed desorption. Unlike hexafluoropentanedione on oxygen-precovered nickel and copper, hexafluoropentanedione does not etch oxygen-precovered platinum. Hexafluoropentanedione decomposes below 350 K, yielding acetaldehyde, trifluoroacetone, and carbon that remains on the surface. An unidentified compound desorbs from the surface as well. The decomposition of hexafluoropentanedione on O/Pt(110) means that it will not be a good etchant for platinum.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemical Engineering
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Ford, Laura Page
- Contributors dc:contributor
-
- Masel, Richard I.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI9944853
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/82467