Part~I: Determination of Quadrupole Couplings via L-Band, B(0) // B(1) EPR. Part~II: Surface Interactions of Perylene Adsorbed on Oxide Powders

Nuclei in the environment (matrix) of the radicals were also probed by ENDOR spectroscopy. Depending on the nature of the sample and experimental conditions, signals could be detected from $\sp1$H, $\sp2$D, and $\sp{27}$Al. The source and behavior of these signals are investigated with special attention paid to contrasting the data from the alumina and silica-alumina substrates. The results suggest that the radicals, although themselves similar, occupy sites of significantly different environment.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2014

Author dc:creator

• Rothenberger, Kurt Summers

Contributors dc:contributor

• Belford, R. Linn

• Chemistry, Inorganic
• Chemistry, Physical

Identifier

(UMI)AAI8908817

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/70431