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University of Illinois at Urbana-Champaign
Structure and Reactivity of Aryl Carbenes and Aryl Nitrenes: Experimental and Computational Approaches
Abstract
dc:descriptionPart one. Three isomeric aryl carbenes, 1,8-diaza-9-fluorenylidene (18DFL), 3,6-diaza-9-fluorenylidene (36DFL), and 4,5-diaza-9-fluorenylidene (45DFL) were generated by photolyses of their corresponding diazo compounds. The physical and chemical behaviors of the diazo compounds and carbenes were examined and compared with their parent system, diazofluorene (DAF) and fluorenylidene (FL).
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2014
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Li, Yu Zhuo
- Contributors dc:contributor
-
- Schuster, Gary B.
Subjects
dc:subject × 1Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8908752
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/70427