Multinuclear Solid-State NMR Studies of Supported Transition Metal Carbonyls

High field carbon-13 and oxygen-17 nuclear magnetic resonance (NMR) spectra have been obtained for a variety of transition metal carbonyl clusters, metal oxides, and oxide-supported metal carbonyl complexes. Magic-angle spinning (MAS) C-13 NMR spectra of polycrystalline metal carbonyl clusters yield both isotropic chemical shifts and chemical shift anisotropies (CSA's) for the carbonyl ligands, providing information on solid-state symmetry, J-coupling, and carbonyl exchange processes.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2014

Author dc:creator

• Walter, Thomas Henry

Contributors dc:contributor

• Oldfield, Eric

• Chemistry, Analytical

Identifier

(UMI)AAI8815437

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/70404