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University of Illinois at Urbana-Champaign

Synthesis and Claisen Rearrangement of Alpha-Ethoxyallyl Vinyl Ethers. Evidence for a Dipolar Transition State

Abstract

dc:description

The product stereoselectivity, scope, and mechanism of the Claisen-Micheal reaction (8 $\rightarrow$ 11) were explored. The products (e.g. 11) of the Claisen-Micheal reaction, which are enol ethers, are protected equivalents of the adducts obtained from the Micheal reaction of α,β-enals with activated carbonyl compounds.$$\vbox{\vskip72pt}$$==>>>

Degree

thesis:*
Name thesis:degree_name
Ph.D.
Level thesis:degree_level
Dissertation
Discipline thesis:degree_discipline
Chemistry
Grantor
University of Illinois at Urbana-Champaign
Year dc:date
1987

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Rogers, Brian Daniel

Subjects

dc:subject × 1

Identifiers

dc:identifier.*
Identifier
(UMI)AAI8721744
OAI identifier oai:identifier
oai:www.ideals.illinois.edu:2142/70379

Chain of custody

source
Harvested from
University of Illinois - Urbana-Champaign
Base URL
www.ideals.illinois.edu/oai-pmh
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Rogers, Brian Daniel. Synthesis and Claisen Rearrangement of Alpha-Ethoxyallyl Vinyl Ethers. Evidence for a Dipolar Transition State. Dissertation thesis, University of Illinois at Urbana-Champaign, 1987. http://hdl.handle.net/2142/70379