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University of Illinois at Urbana-Champaign
Multinuclear Nuclear Magnetic Resonance Studies of Model Inorganic Systems (Nmr)
Abstract
dc:descriptionA variety of techniques are employed to obtain information from molybdenum carbonyl on (gamma)-aluminum, the Group IIIA compounds, Al III and silica hydrolysis. Techniques such as rapid magic-angle sample spinning (MASS) of glass sealed samples are used to investigate the highly air sensitive system molybdenum carbonyl on (gamma)-alumina by carbon-13 NMR spectroscopy. The results obtained suggest the presence of very mobile physisorbed molybdenum hexacarbonyl. The two subcarbonyls molybdenum penta-carbonyl and tri-carbonyl are shown to be the most consistent with the data as products after thermal activation.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2014
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Thompson, Arthur Robert
Subjects
dc:subject × 1Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8711893
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/70366