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University of Illinois at Urbana-Champaign
Electron Transfer in Mixed-Valence Binuclear Ferrocenes
Abstract
dc:descriptionA single quadrupole-splint doublet is seen in the 4.5 K Mossbauer spectrum for the triiodide salt of 3-acetylbis-(fulvalene)diiron(1+). An IT band at 7140 cm('-1) (e = 1740 M('-1) cm('-1)) is evident in the electronic absorption spectrum. A relatively isotropic EPR signal and a C-H bending band at 840 cm('-1) in the IR spectrum also indicate a delocalized electronic structure.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2014
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Moore, Michael Francis
Subjects
dc:subject × 1Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8600272
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/70314