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University of Illinois at Urbana-Champaign
Compounds of Pentacoordinate (10-Boron-5) and Hexacoordinate (12-Boron-6) Hypervalent Boron
Abstract
dc:descriptionEfficient synthetic routes to 2-substituted pyridines and 2,6-disubstituted pyridine 1-oxides are described, involving direct ortho lithiation with the sterically hindered base, lithium 2,2,6,6-tetramethylpiperidide, in the presence of electrophiles that are compatible with the base, e.g., trimethylsilyl chloride and hexafluoroacetone.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2014
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Lee, David Yen
Subjects
dc:subject × 1Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8600249
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/70313