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University of Illinois at Urbana-Champaign

A Stopped-Flow Analyzer for Kinetic Methods Development - Automated Implementation of Guggenheim's Methods

Abstract

dc:description

Accessories have been designed and constructed which directly transform a conventional single-beam spectrophotometer into a versatile stopped-flow kinetic analyzer. A relatively inexpensive microcomputer system serves as a dedicated controller/data processor for the instrument. The design employed features preservation of the optical configuration and geometry of the original spectrophotometer. Thus, abilities related to the performance of precise, absolute absorbance measurements have been retained. Additionally, kinetic response curves can be reproducibly generated, primarily due to efficiencies on solution transport and mixing components built into the "stopped-flow module". The hybrid nature of the instrument, allowing reliable collection and processing of responses from both kinetic and equilibrium phases of reactions, is seen as a powerful attribute.

Degree

thesis:*
Name thesis:degree_name
Ph.D.
Level thesis:degree_level
Dissertation
Discipline thesis:degree_discipline
Chemistry
Grantor
University of Illinois at Urbana-Champaign
Year dc:date
2014

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Seiler, Brian Douglas

Subjects

dc:subject × 1

Identifiers

dc:identifier.*
Identifier
(UMI)AAI8324641
OAI identifier oai:identifier
oai:www.ideals.illinois.edu:2142/70227

Chain of custody

source
Harvested from
University of Illinois - Urbana-Champaign
Base URL
www.ideals.illinois.edu/oai-pmh
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Seiler, Brian Douglas. A Stopped-Flow Analyzer for Kinetic Methods Development - Automated Implementation of Guggenheim's Methods. Dissertation thesis, University of Illinois at Urbana-Champaign, 2014. http://hdl.handle.net/2142/70227