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University of Illinois at Urbana-Champaign
Part One: Ozonolysis of Diphenylvinylene Carbonate. Synthesis and Thermolysis of Dibenzoyl Monoperoxycarbonate. Part Two: Singlet Oxygen: The Lifetime of Singlet Oxygen in Solution and Its Reaction With Ene-Type Olefins
Abstract
dc:descriptionThe reaction of ozone and diphenylvinylene carbonate is found to give dibenzoyl monoperoxycarbonate in good yield. A mechanism for the formation of this peroxide is proposed and is consistent with the Criegee mechanism for ozonolysis of most olefins. The thermolysis of dibenzoyl monoperoxycarbonate in benzene is also reported. The products of that thermolysis are very similar to the products of benzoyl peroxide thermolysis, but the rate of decay is significantly faster. The activation parameters for the decay of dibenzoyl monoperoxycarbonate were found to be consistent with the simultaneous cleavage of two bonds in the initial step.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2014
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Hurst, John Robert
Subjects
dc:subject × 1Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8324579
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/70222