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University of Illinois at Urbana-Champaign
Selective Gamma Substitution of Alpha-Trimethylsilyl-Beta,gamma-Unsaturated Esters
Abstract
dc:descriptionA variety of methods were investigated in order to synthesize (alpha)-silyl-(beta),(gamma)-unsaturated esters. Although a nickel-catalyzed coupling reaction of vinyl bromides with lithium ethyl (alpha)-trimethylsilylacetate was employed to synthesize those esters utilized in subsequent reactions, an alternative method, viz. synthesis of the corresponding (alpha)-silyl-(alpha),(beta)-unsaturated ester followed by deconjugation, is deemed as more promising.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2014
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Albaugh-Robertson, Pamela
Subjects
dc:subject × 1Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8302790
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/70192