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University of Illinois at Urbana-Champaign
Preparation and Chemiluminescence of Cyclopropyl-Substituted Malonyl Peroxides
Abstract
dc:description4-Spiro{(2'-spirocyclopropyl)-cyclohexyl}-1,2-dioxolane-3,5-dione (2) and 4-cyclopropyl-4-methyl-1,2-dioxolane-3,5-dione (1) are prepared by the reaction of dicyclohexylcarbodiimide and hydrogen peroxide with the parent malonic acids. Chemiluminescence is observed when the cyclopropyl-substituted malonyl peroxides, 1 and 2, are heated in the presence of added aromatic fluorescers. The chemiluminescence is explained by the activated CIEEL mechanism with the aromatic fluorescer and malonyl peroxide. A cyclopropylcarbinyl-allylcarbinyl radical rearrangement is proposed to be involved in the chemiluminescence mechanism.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 1982
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Darmon, Michael John
Subjects
dc:subject × 1Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8218452
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/70187