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University of Illinois at Urbana-Champaign
One Electron Reduction of Sulfonium Salts: A Mechanistic Study
Abstract
dc:descriptionTwenty-three phenylsulfonium salts have been reduced to sulfides using the heterogeneous intercalation compound potassium/graphite (KC(,8)). The products, consisting of sulfides and hydrocarbons, have been identified by glc, ('1)H NMR and mass spectroscopic comparison to authentic material, and/or elemental analysis. The systems studied were acyclic (1), cyclic (2), and benzofused cyclic (3) sulfonium salts.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2014
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Sullivan, Thomas Allen
Subjects
dc:subject × 1Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8203608
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/70177