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University of Illinois at Urbana-Champaign

The Effects of High Pressure on The Photovoltage Spectrum of Cadmium-Sulfide and Cadmium-Selenide Schottky Diodes

Abstract

dc:description

The effects of high pressure to 10 kilobars on the photovoltage spectrum of CdS and CdSe Schottky diodes has been investigated. These diodes exhibit a photovoltage at photon energies less than the energy gap of the semiconductor. This photovoltage is due to excitation of electrons from interface states to the conduction band of the semiconductor. A model where the interaction of the diode contact metal with the semiconductor surface gives rise to a sub-band of interface energy levels is used to explain the low energy response. Excitations from the sub-band also give rise to a recombination mechanism which causes a decrease in the photovoltage at photon energies slightly less than the semiconductor band gap energy. The recombination level is defined as the energy at which the recombination of photogenerated electrons and holes begins to dominate the photovoltage spectrum.

Degree

thesis:*
Name thesis:degree_name
Ph.D.
Level thesis:degree_level
Dissertation
Discipline thesis:degree_discipline
Chemical Engineering
Grantor
University of Illinois at Urbana-Champaign
Year dc:date
2014

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Zurawsky, Walter Peter

Subjects

dc:subject × 1

Identifiers

dc:identifier.*
Identifier
(UMI)AAI8502355
OAI identifier oai:identifier
oai:www.ideals.illinois.edu:2142/69750

Chain of custody

source
Harvested from
University of Illinois - Urbana-Champaign
Base URL
www.ideals.illinois.edu/oai-pmh
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Zurawsky, Walter Peter. The Effects of High Pressure on The Photovoltage Spectrum of Cadmium-Sulfide and Cadmium-Selenide Schottky Diodes. Dissertation thesis, University of Illinois at Urbana-Champaign, 2014. http://hdl.handle.net/2142/69750