An x-ray study of the structure of K1-xRbxCy

The mixed layered compounds K1-xRbxC8 and K1-xRbxC24 represent quasi two-dimensional alloys interleaved by graphite hexagonal planes. We report extensive x-ray scattering investigations of the structural aspects of these compounds. In stage 1 K1-xRbxC8, we find that the interlayer separation exhibits a slight deviation from linearity, independent of the graphite material used (pyrolytic graphite or single crystals), with a maximum deviation centered at x=2/3. In the plane, the mixed alkali layers form a (2x2)R0° superstructure with complete site disorder among the K and Rb metal atoms. Extensive low temperature investigations have not revealed any tendency of the mixed layer to either super-order or phase separate. The stacking sequence is independent of alloy composition and is identical to the stacking sequence in KC8 as well as in RbC8. The carbon-carbon bond length appears not to change with alloy composition. By comparing the diffusion constants from a macroscopic diffusion experiment with self diffusion constants obtained from quasi-elastic neutron scattering data, we found that the substitutional intercalation process must be drastically hindered by a barrier at the perimeter of the sample. The stage 2 K1-xRbxC24 (x-0.52,0.80) compounds were synthesized for the first time. Below the ordering temperature (Tu-149 and 159K, respectively) peaks corresponding to a discommensuration domain structure are observed, which correspond to the compositional average of the unmixed compounds. By taking single crystal Laue photographs, we have determined the position and orientation of the peaks near the origin. We propose a simple physical model to interpret the x-ray data. Below a second transition temperature TL~ lOOK, the domain structure becomes unstable against a composition modulation.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Physics

Year dc:date

2012

Author dc:creator

• Chow, Paul C.

Contributors dc:contributor

• Zabel, Hartmut

• x-ray
• quasi two-dimensional alloy

Statement dc:rights

• 1988 Paul C. Chow

Language dc:language

en

Handle dc:identifier

http://hdl.handle.net/2142/28683

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/28683