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University of Illinois at Urbana-Champaign
Beta-lithiations of carboxamides: An investigation of the regio- and stereoselectivity of directed lithiations
Abstract
dc:descriptionAn investigation of the diastereoselective β-metalation and of the structure of a carbanion of a β-phenyl tertiary amide has been carried out. The directed metalation has been found to occur with high diastereoselectivity and the resulting carbanion is best described as a pyramidal benzyllithium species based on $\sp{13}$C NMR evidence.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry, Organic
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2011
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Lutz, Gary Paul
- Contributors dc:contributor
-
- Beak, Peter
Subjects
dc:subject × 1Rights
dc:rights- Statement dc:rights
-
- Copyright 1991 Lutz, Gary Paul
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
-
AAI9210904
(UMI)AAI9210904 - OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/23798