"Low-valent early transition metal complexes stabilized by the chelating tripod phosphine ligand ( t-butyl)tris((dimethylphosphino)methyl);silane (""trimpsi"")"

"The organometallic chemistry of the early first-row metals has been extended through the use of a new tridentate phosphine ligand, Bu$\sp{\rm t}$Si(CH$\sb2$PMe$\sb2$)$\sb3$, or ""trimpsi"". The starting materials (trimpsi)TiCl$\sb3$(thf), (trimpsi)VCl$\sb3$(thf), (trimpsi)CrCl$\sb3$, and (trimpsi)ZrCl$\sb4$(dme) have been used to prepare new carbonyl, arene, and alkyl complexes of the early transition metals."

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Gardner, Thomas George

• Chemistry, Inorganic

Statement dc:rights

• Copyright 1989 Gardner, Thomas George

Language dc:language

eng

Identifier

AAI9010859
(UMI)AAI9010859

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/23041