S(N)2' reactions of chiral allylic carbamates with organocopper reagents. Asymmetric synthesis of tertiary and quarternary carbon centers

The chiral auxiliary-based, asymmetric S$\sb{\rm N}2\sp\prime$ cuprate reactions of allylic carbamates were examined. The amine and amino ether auxiliaries were evaluated based on the enantioselectivities each provided in the reactions of the carbamates with methylcopper. The effects of varying the geometry and substitution pattern of the olefin in the carbamates were also studied.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Marble, Lyndon Kenneth

Contributors dc:contributor

• Denmark, Scott E.

• Chemistry, Organic

Statement dc:rights

• Copyright 1991 Marble, Lyndon Kenneth

Language dc:language

eng

Identifier

AAI9124458
(UMI)AAI9124458

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/22879