Multinuclear NMR studies on solution structures and dynamics of triosmium hydrido carbonyl phosphine cluster compounds

The reaction of (μ-H)$\sb2$Os$\sb3$(CO)$\sb9$(PPh$\sb3$) with acetylene at room temperature provides two isomers of a hydridovinyl cluster. The solid-state structure of each isomer has been determined by single-crystal X-ray crystallography. The solution structures and dynamics have been studied by extensive $\sp{13}$C NMR studies, including $\sp{13}$C$\{\sp1$H$\}$ COSY and $\sp{13}$C spin saturation transfer experiments.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Koike, Makoto

Contributors dc:contributor

• Shapley, John R.

• Chemistry, Inorganic

Statement dc:rights

• Copyright 1991 Koike, Makoto

Language dc:language

eng

Identifier

AAI9210874
(UMI)AAI9210874

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/22734