Competing reaction pathways in the photochemical reactions of metal carbonyl compounds

The photochemical reaction of Mn$\sb2$(CO)$\sb{10}$ with HSnBu$\sb3$ has been studied by continuous photolysis. Sunlamp irradiation of a CO-saturated hexane solution of Mn$\sb2$(CO)$\sb{10}$ and HSnBu$\sb3$ results in formation of HMn(CO)$\sb5$ and Bu$\sb3$SnMn(CO)$\sb5$ in equimolar quantities. The rate of disappearance of Mn$\sb2$(CO)$\sb{10}$ and formation of products exhibit an inverse (CO) dependence.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Sullivan, Richard Joseph

Contributors dc:contributor

• Brown, Theodore L.

• Chemistry, Inorganic

Statement dc:rights

• Copyright 1990 Sullivan, Richard Joseph

Language dc:language

eng

Identifier

AAI9114428
(UMI)AAI9114428

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/22666