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University of Illinois at Urbana-Champaign
Inter- and intramolecular (4+2) cycloaddition reactions and tandem inter- and intramolecular (4+2)/intramolecular (3+2)cycloaddition reactions of nitroalkenes
Abstract
dc:descriptionBoth inter- and intramolecular cycloadditions of nitroalkenes with Lewis acid catalysis were investigated. The intramolecular cycloadditions of nitroalkenes were found to be completely stereoselective for trisubstituted nitroalkenes. Intermolecular cycloadditions of aromatic nitroalkenes were found to proceed with extremely high selectivity. It was found that E-nitroalkenes can be prepared from aldehydes using acetylation/dehydroacetylation method.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2011
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Moon, Young Choon
- Contributors dc:contributor
-
- Denmark, Scott E.
Subjects
dc:subject × 1Rights
dc:rights- Statement dc:rights
-
- Copyright 1991 Moon, Young Choon
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
-
AAI9210924
(UMI)AAI9210924 - OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/22129