Synthesis and properties of mononuclear and polynuclear indenyl iridium complexes

The reaction of $\rm Ir(CO)\sb2(\eta\sp5$-$\rm C\sb9H\sb7)$ with $\rm Ir(\eta\sp2$-$\rm C\sb2H\sb4)\sb2(\eta\sp5$-$\rm C\sb9H\sb7)$ provided \rm Ir\sb3(μ-$\rm CO)\sb3(\eta\sp5$-$\rm C\sb9H\sb7)\sb3$, and the reaction of $\rm Ir(CO)\sb2(\eta\sp5$-$\rm C\sb9H\sb7)$ with $\rm Rh(\eta\sp2$-$\rm C\sb2H\sb4)\sb2(\eta\sp5$-$\rm C\sb9H\sb7)$ provided \rm Ir\sb{3-x}Rh\sb{x}(μ-$\rm CO)\sb3(\eta\sp5$-$\rm C\sb9H\sb7)\sb3$ (x = 0 - 3) in good yields. These compounds react readily with carbon monoxide or PPh$\sb3$ at room temperature to form mononuclear products.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Comstock, Matthew Christian

Contributors dc:contributor

• Shapley, John R.

• Chemistry, Inorganic

Statement dc:rights

• Copyright 1996 Comstock, Matthew Christian

Language dc:language

eng

Identifier

9780591197792
AAI9712238
(UMI)AAI9712238

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/20150