Synthetic methods and studies of some 10-Y-5 and 12-Y-6 hypervalent main group element species of group IIIB

N,N,N-tributylbutanaminium(OC-6-11$\sp\prime$)-bis (4-(1,1-dimethylethyl)-α,α,α\sp\primeα\sp\prime-tetrakis(trifluoromethyl)-2,6-pyridinedimethanolato(2-)N1,Oα,Oα\sp\prime) aluminum, a 12-Al-6 anionic species was synthesized and experimentally examined. Neutral mono-protonated and mono-methylated products of this anion were synthesized and studied. X-ray crystallography was used to establish the structure of the octahedral 12-Al-6 species and its protonated analogue. The protonated species was a distorted octahedral species with the proton hydrogen-bonding two of the apical oxygens.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Hoglen, Dean Kent

Contributors dc:contributor

• Martin, J.C.

• Chemistry, Organic

Statement dc:rights

• Copyright 1990 Hoglen, Dean Kent

Language dc:language

eng

Identifier

AAI9026207
(UMI)AAI9026207

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/20053