Transmission electron microscopy investigation of ion implantation damage in gallium arsenide and other semiconductors

The crystalline-to-amorphous transition induced by ion implantation was investigated in GaAs and GaP using transmission electron microscopy. The experiments included those performed in situ using the HVEM-Tandem Accelerator Facility at Argonne National Laboratory and also those performed using high-resolution TEM. The implantations were made with Ar$\sp+$, Kr$\sp+$, Xe$\sp+$, and Au$\sp+$ ions (energy 50 or 80 keV) at 30 and 300 K. The high-resolution experiments confirmed the amorphous nature of the damage produced in individual displacement cascades. The in situ experiments at 30 K showed that amorphous zones are produced within isolated cascades with high probability. It was found that the efficiency of production of amorphous damage increases with increasing ion mass. The probability that an individual cascade will generate an amorphous region decreases when the implantation is performed at room temperature in GaAs but remains the same for GaP. Annealing experiments in the 30-300 K range demonstrated that there is significant damage recovery below 300 K in GaAs but none in GaP. Calculations of the energy density deposited in the cascades, determined through Monte-Carlo simulations, suggest that the formation and subsequent quenching of a molten zone may be responsible for the production of the amorphous damage.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Materials Science and Engineering

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Bench, Michael Wayne

Contributors dc:contributor

• Robertson, Ian M.

• Physics, Condensed Matter
• Engineering, Materials Science

Statement dc:rights

• Copyright 1992 Bench, Michael Wayne

Language dc:language

eng

Identifier

AAI9305465
(UMI)AAI9305465

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/19995