Synthetic and chromatographic study of the spiro-lactams and spiro-lactones based on a 9',10'-dihydro-(9,10)-ethanoanthracene Diels-Alder adduct. Application of flash vacuum thermolysis towards synthesis of exo-methylene lactones and lactams

Synthesis of a variety of spiro-lactams and spiro-lactones which are based on a 9$\sp\prime$,10$\sp\prime$-dihydro- (9,10) -ethanoanthracene Diels-Alder adduct has been performed. Control of relative stereochemistry at the C2 and C2, C3 carbons on the lactone ring during synthesis of the spiro-lactones has been observed and is dependent on the reaction temperature and the length of reaction time.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Gruber, James Vincent

Contributors dc:contributor

• Pirkle, William H.

• Organic Chemistry

Statement dc:rights

• Copyright 1989 Gruber, James Vincent

Language dc:language

eng

Identifier

AAI8916255
(UMI)AAI8916255

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/19026