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Monterey, CA; Naval Postgraduate School

The kinetics of successive aquation reactions of tetraamminepalladium (II) ion

Abstract

dc:description.abstract

Solutions of tetraamminepalladium (II) perchlorate were made up and analyzed. The following acid hydrolysis reactions of tetraamminepalladium (II) ion were studied by ultraviolet spectroscopy. First order rate constants were evaluated for each step of the reaction series at various temperatures. Activation parameters were determined. (Equations) Mechanisms for the consecutive reactions are proposed, and cis and trans effects are discussed.

Degree

thesis:*
Department dc:contributor.department
Material Science and Chemistry
Grantor dc:publisher
Monterey, CA; Naval Postgraduate School
Year dc:date.issued
1971

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • DeBerry, William Jennings, Jr.
Advisor dc:contributor.advisor
  • Reinhardt, Richard A.

Rights

dc:rights
Statement dc:rights
  • This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States.

Identifiers

dc:identifier.*
Handle dc:identifier.uri
https://hdl.handle.net/10945/15789
OAI identifier oai:identifier
oai:calhoun.nps.edu:10945/15789

Chain of custody

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Naval Postgraduate School
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Last updated
2026-07-27
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citation

DeBerry, William Jennings, Jr.. The kinetics of successive aquation reactions of tetraamminepalladium (II) ion. Monterey, CA; Naval Postgraduate School, 1971. https://hdl.handle.net/10945/15789