{"id":{"repo_id":"nps","oai_identifier":"oai:calhoun.nps.edu:10945/15789"},"canonical_url":"https://search.dev.ndltd.org/etd/nps/oai:calhoun.nps.edu:10945/15789","repository":{"repo_id":"nps","name":"Naval Postgraduate School","base_url":"https://calhoun.nps.edu/server/oai/request"},"display":{"title":"The kinetics of successive aquation reactions of tetraamminepalladium (II) ion","abstract":"Solutions of tetraamminepalladium (II) perchlorate were made up and analyzed. The following acid hydrolysis reactions of tetraamminepalladium (II) ion were studied by ultraviolet spectroscopy. First order rate constants were evaluated for each step of the reaction series at various temperatures. Activation parameters were determined. (Equations) Mechanisms for the consecutive reactions are proposed, and cis and trans effects are discussed.","abstract_html":"Solutions of tetraamminepalladium (II) perchlorate were made up and analyzed. The following acid hydrolysis reactions of tetraamminepalladium (II) ion were studied by ultraviolet spectroscopy. First order rate constants were evaluated for each step of the reaction series at various temperatures. Activation parameters were determined. (Equations) Mechanisms for the consecutive reactions are proposed, and cis and trans effects are discussed.","abstract_has_math":false,"creators":["DeBerry, William Jennings, Jr."],"institution":"Monterey, CA; Naval Postgraduate School","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":"Material Science and Chemistry","school":null,"contributors":[],"advisors":["Reinhardt, Richard A."],"committee_chairs":[],"committee_members":[],"year":1971,"date_issued":"1971-06","date_published":"1971-06","updated_at":"2026-07-27T20:27:01Z","subjects":[],"languages":[],"rights":["This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/10945/15789","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Reinhardt, Richard A."]},{"key":"dc:contributor.department","label":"Department","values":["Material Science and Chemistry"]},{"key":"dc:creator","label":"Author","values":["DeBerry, William Jennings, Jr."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2012-11-13T23:24:31Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2012-11-13T23:24:31Z"]},{"key":"dc:date.issued","label":"Date","values":["1971-06"]},{"key":"dc:publisher","label":"Institution","values":["Monterey, CA; Naval Postgraduate School"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:rights","label":"Dc Rights","values":["This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["https://hdl.handle.net/10945/15789"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["Solutions of tetraamminepalladium (II) perchlorate were made up and analyzed. The following acid hydrolysis reactions of tetraamminepalladium (II) ion were studied by ultraviolet spectroscopy. First order rate constants were evaluated for each step of the reaction series at various temperatures. Activation parameters were determined. (Equations) Mechanisms for the consecutive reactions are proposed, and cis and trans effects are discussed."]},{"key":"dc:title","label":"Title","values":["The kinetics of successive aquation reactions of tetraamminepalladium (II) ion"]}]}],"canonical_facts":{"dc:contributor.advisor":["Reinhardt, Richard A."],"dc:contributor.department":["Material Science and Chemistry"],"dc:creator":["DeBerry, William Jennings, Jr."],"dc:date.accessioned":["2012-11-13T23:24:31Z"],"dc:date.available":["2012-11-13T23:24:31Z"],"dc:date.issued":["1971-06"],"dc:description.abstract":["Solutions of tetraamminepalladium (II) perchlorate were made up and analyzed. The following acid hydrolysis reactions of tetraamminepalladium (II) ion were studied by ultraviolet spectroscopy. First order rate constants were evaluated for each step of the reaction series at various temperatures. Activation parameters were determined. (Equations) Mechanisms for the consecutive reactions are proposed, and cis and trans effects are discussed."],"dc:identifier.uri":["https://hdl.handle.net/10945/15789"],"dc:publisher":["Monterey, CA; Naval Postgraduate School"],"dc:rights":["This publication is a work of the U.S. Government as defined in Title 17, United States Code, Section 101. Copyright protection is not available for this work in the United States."],"dc:title":["The kinetics of successive aquation reactions of tetraamminepalladium (II) ion"],"dc:type":["Thesis"]},"updated_at":"2026-07-27T20:27:01Z"}