Synthesis and reactivity of Rh and Ir imino and azidophosphonamido complexes

This work reports a family of iminophosphonamido Rh and Ir cyclooctadiene (COD) complexes, [Ph2P(NR)2]M(COD), where the substituents on nitrogen vary, R = 2,4,6-trimethylphenyl (Mes) or adamantyl (Ad). The reaction chemistry of the iminophosphonamido Rh and Ir COD complexes was probed. This work also demonstrates the synthetic route to and of a family of azidophosphonamide Rh and Ir phosphazide containing ligand cyclooctadiene (COD) complexes, [Ph2P(N3R)(NR])M(COD). The unusual ligand linkage isomerism of said species is discussed. Preliminary results pertaining to bis(cyclooctene) (COE) complexes bearing both ligand types are also reported.

Grantor dc:publisher

Lethbridge, Alta. : University of Lethbridge, Dept. of Chemistry and Biochemistry

Year dc:date.issued

2022

Authors dc:creator

• Cruz-Milette, Daisy E.
• University of Lethbridge. Faculty of Arts and Science

Advisor dc:contributor.supervisor

• Hayes, Paul G.

• Ligands
• Coordination chemistry
• Iminophosphonamide
• Azidophosphonamide

Language dc:language.iso

en_CA

Identifier

hdl:10133/6408

OAI record oai:identifier

https://opus.uleth.ca/server/oai/request?verb=GetRecord&metadataPrefix=dim&identifier=oai%3Aopus.uleth.ca%3A10133%2F6408