{"id":{"repo_id":"lethbridge","oai_identifier":"oai:opus.uleth.ca:10133/6408"},"canonical_url":"https://search.dev.ndltd.org/etd/lethbridge/oai:opus.uleth.ca:10133/6408","repository":{"repo_id":"lethbridge","name":"University of Lethbridge","base_url":"https://opus.uleth.ca/server/oai/request"},"display":{"title":"Synthesis and reactivity of Rh and Ir imino and azidophosphonamido complexes","abstract":"This work reports a family of iminophosphonamido Rh and Ir cyclooctadiene (COD) complexes, [Ph2P(NR)2]M(COD), where the substituents on nitrogen vary, R = 2,4,6-trimethylphenyl (Mes) or adamantyl (Ad). The reaction chemistry of the iminophosphonamido Rh and Ir COD complexes was probed. This work also demonstrates the synthetic route to and of a family of azidophosphonamide Rh and Ir phosphazide containing ligand cyclooctadiene (COD) complexes, [Ph2P(N3R)(NR])M(COD). The unusual ligand linkage isomerism of said species is discussed. Preliminary results pertaining to bis(cyclooctene) (COE) complexes bearing both ligand types are also reported.","abstract_html":"This work reports a family of iminophosphonamido Rh and Ir cyclooctadiene (COD) complexes, [Ph2P(NR)2]M(COD), where the substituents on nitrogen vary, R = 2,4,6-trimethylphenyl (Mes) or adamantyl (Ad). The reaction chemistry of the iminophosphonamido Rh and Ir COD complexes was probed. This work also demonstrates the synthetic route to and of a family of azidophosphonamide Rh and Ir phosphazide containing ligand cyclooctadiene (COD) complexes, [Ph2P(N3R)(NR])M(COD). The unusual ligand linkage isomerism of said species is discussed. Preliminary results pertaining to bis(cyclooctene) (COE) complexes bearing both ligand types are also reported.","abstract_has_math":false,"creators":["Cruz-Milette, Daisy E.","University of Lethbridge. Faculty of Arts and Science"],"institution":"Lethbridge, Alta. : University of Lethbridge, Dept. of Chemistry and Biochemistry","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Hayes, Paul G."],"committee_chairs":[],"committee_members":[],"year":2022,"date_issued":"2022","date_published":"2022","updated_at":"2026-08-21T16:45:55Z","subjects":["Ligands","Coordination chemistry","Iminophosphonamide","Azidophosphonamide"],"languages":["en_CA"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["hdl:10133/6408"],"render_values":[{"text":"hdl:10133/6408","href":null,"code":true}]}]},"links":{"outbound_url":"https://hdl.handle.net/10133/6408","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"source_record":{"url":"https://opus.uleth.ca/server/oai/request?verb=GetRecord&metadataPrefix=dim&identifier=oai%3Aopus.uleth.ca%3A10133%2F6408","prefix":"dim"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.supervisor","label":"Supervisor","values":["Hayes, Paul G."]},{"key":"dc:creator","label":"Author","values":["Cruz-Milette, Daisy E.","University of Lethbridge. 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The reaction chemistry of the iminophosphonamido Rh and Ir COD complexes was probed. This work also demonstrates the synthetic route to and of a family of azidophosphonamide Rh and Ir phosphazide containing ligand cyclooctadiene (COD) complexes, [Ph2P(N3R)(NR])M(COD). The unusual ligand linkage isomerism of said species is discussed. Preliminary results pertaining to bis(cyclooctene) (COE) complexes bearing both ligand types are also reported."]},{"key":"dc:description.other","label":"Dc Description Other","values":["This work reports a family of iminophosphonamido Rh and Ir cyclooctadiene (COD) complexes, [Ph2P(NR)2]M(COD), where the substituents on nitrogen vary, R = 2,4,6-trimethylphenyl (Mes) or adamantyl (Ad). The reaction chemistry of the iminophosphonamido Rh and Ir COD complexes was probed. This work also demonstrates the synthetic route to and of a family of azidophosphonamide Rh and Ir phosphazide containing ligand cyclooctadiene (COD) complexes, [Ph2P(N3R)(NR])M(COD). The unusual ligand linkage isomerism of said species is discussed. Preliminary results pertaining to bis(cyclooctene) (COE) complexes bearing both ligand types are also reported."]},{"key":"dc:title","label":"Title","values":["Synthesis and reactivity of Rh and Ir imino and azidophosphonamido complexes"]}]}],"canonical_facts":{"dc:contributor.supervisor":["Hayes, Paul G."],"dc:creator":["Cruz-Milette, Daisy E.","University of Lethbridge. Faculty of Arts and Science"],"dc:date.accessioned":["2023-01-17T22:22:39Z"],"dc:date.available":["2023-01-17T22:22:39Z"],"dc:date.issued":["2022"],"dc:description.abstract":["This work reports a family of iminophosphonamido Rh and Ir cyclooctadiene (COD) complexes, [Ph2P(NR)2]M(COD), where the substituents on nitrogen vary, R = 2,4,6-trimethylphenyl (Mes) or adamantyl (Ad). The reaction chemistry of the iminophosphonamido Rh and Ir COD complexes was probed. This work also demonstrates the synthetic route to and of a family of azidophosphonamide Rh and Ir phosphazide containing ligand cyclooctadiene (COD) complexes, [Ph2P(N3R)(NR])M(COD). The unusual ligand linkage isomerism of said species is discussed. Preliminary results pertaining to bis(cyclooctene) (COE) complexes bearing both ligand types are also reported."],"dc:description.other":["This work reports a family of iminophosphonamido Rh and Ir cyclooctadiene (COD) complexes, [Ph2P(NR)2]M(COD), where the substituents on nitrogen vary, R = 2,4,6-trimethylphenyl (Mes) or adamantyl (Ad). The reaction chemistry of the iminophosphonamido Rh and Ir COD complexes was probed. This work also demonstrates the synthetic route to and of a family of azidophosphonamide Rh and Ir phosphazide containing ligand cyclooctadiene (COD) complexes, [Ph2P(N3R)(NR])M(COD). The unusual ligand linkage isomerism of said species is discussed. Preliminary results pertaining to bis(cyclooctene) (COE) complexes bearing both ligand types are also reported."],"dc:identifier":["hdl:10133/6408"],"dc:identifier.uri":["https://hdl.handle.net/10133/6408"],"dc:language.iso":["en_CA"],"dc:publisher":["Lethbridge, Alta. : University of Lethbridge, Dept. of Chemistry and Biochemistry"],"dc:publisher.department":["Department of Chemistry & Biochemistry"],"dc:subject":["Ligands","Coordination chemistry","Iminophosphonamide","Azidophosphonamide"],"dc:title":["Synthesis and reactivity of Rh and Ir imino and azidophosphonamido complexes"],"dc:type":["Thesis"]},"updated_at":"2026-08-21T16:45:55Z"}