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Central Washington University

Preparation of Phenylsulphur Chloride Tetrafluoride

Abstract

dc:description.abstract

The reaction of C6H5SF3, CSF and C12 was studied under a variety of conditions. The reaction run in the presence of a trace of water yielded C6H5SO2F and C1C6H4SO2F. The reaction run in stainless steel at 170°C yielded an amber solid believed to be a polymer with the empirical formula C6H3.67SF2. Chlorination of a C6H5SF3-CSF mixture in monel at 220°C yielded a yellow liquid tentatively identified as a mixture of the new species C6H5SF4C1, FC6H4SF4C1 and C1C6H4SF4C1.

Degree

thesis:*
Name thesis:degree_name
Master of Science (MS)
Discipline thesis:degree_discipline
Chemistry
Year
1968

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Sauer, Dennis T.
Contributors dc:contributor
  • L. Clint Duncan
  • Helmi S. Habib
  • Richard W. Hasbrouck

Subjects

dc:subject × 4

Rights

Language dc:language
English

Identifiers

dc:identifier.*
Repository record dc:identifier
https://digitalcommons.cwu.edu/etd/975
OAI identifier oai:identifier
oai:digitalcommons.cwu.edu:etd-1992

Chain of custody

source
Harvested from
Central Washington University
Base URL
digitalcommons.cwu.edu/do/oai/
Last updated
2026-07-24
Source record
OAI-PMH GetRecord
citation

Sauer, Dennis T.. Preparation of Phenylsulphur Chloride Tetrafluoride. 1968. https://digitalcommons.cwu.edu/etd/975