{"id":{"repo_id":"central-wash","oai_identifier":"oai:digitalcommons.cwu.edu:etd-1992"},"canonical_url":"https://search.dev.ndltd.org/etd/central-wash/oai:digitalcommons.cwu.edu:etd-1992","repository":{"repo_id":"central-wash","name":"Central Washington University","base_url":"https://digitalcommons.cwu.edu/do/oai/"},"display":{"title":"Preparation of Phenylsulphur Chloride Tetrafluoride","abstract":"The reaction of C6H5SF3, CSF and C12 was studied under a variety of conditions. The reaction run in the presence of a trace of water yielded C6H5SO2F and C1C6H4SO2F. The reaction run in stainless steel at 170°C yielded an amber solid believed to be a polymer with the empirical formula C6H3.67SF2. Chlorination of a C6H5SF3-CSF mixture in monel at 220°C yielded a yellow liquid tentatively identified as a mixture of the new species C6H5SF4C1, FC6H4SF4C1 and C1C6H4SF4C1.","abstract_html":"The reaction of C6H5SF3, CSF and C12 was studied under a variety of conditions. The reaction run in the presence of a trace of water yielded C6H5SO2F and C1C6H4SO2F. The reaction run in stainless steel at 170°C yielded an amber solid believed to be a polymer with the empirical formula C6H3.67SF2. Chlorination of a C6H5SF3-CSF mixture in monel at 220°C yielded a yellow liquid tentatively identified as a mixture of the new species C6H5SF4C1, FC6H4SF4C1 and C1C6H4SF4C1.","abstract_has_math":false,"creators":["Sauer, Dennis T."],"institution":null,"degree_name":"Master of Science (MS)","degree_level":null,"degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["L. Clint Duncan","Helmi S. Habib","Richard W. Hasbrouck"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1968,"date_issued":"1968-08-01T07:00:00Z","date_published":"1968-08-01T07:00:00Z","updated_at":"2026-07-24T01:37:23Z","subjects":["Science","Chemistry","Sulfur compounds","Physical Sciences and Mathematics"],"languages":["English"],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://digitalcommons.cwu.edu/etd/975","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["L. Clint Duncan","Helmi S. Habib","Richard W. Hasbrouck"]},{"key":"dc:creator","label":"Author","values":["Sauer, Dennis T."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:type","label":"Dc Type","values":["Text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science (MS)"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Science","Chemistry","Sulfur compounds","Physical Sciences and Mathematics"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["English"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://digitalcommons.cwu.edu/etd/975"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["The reaction of C6H5SF3, CSF and C12 was studied under a variety of conditions. The reaction run in the presence of a trace of water yielded C6H5SO2F and C1C6H4SO2F. The reaction run in stainless steel at 170°C yielded an amber solid believed to be a polymer with the empirical formula C6H3.67SF2. Chlorination of a C6H5SF3-CSF mixture in monel at 220°C yielded a yellow liquid tentatively identified as a mixture of the new species C6H5SF4C1, FC6H4SF4C1 and C1C6H4SF4C1."]},{"key":"dc:title","label":"Title","values":["Preparation of Phenylsulphur Chloride Tetrafluoride"]}]}],"canonical_facts":{"dc:contributor":["L. Clint Duncan","Helmi S. Habib","Richard W. Hasbrouck"],"dc:creator":["Sauer, Dennis T."],"dc:description.abstract":["The reaction of C6H5SF3, CSF and C12 was studied under a variety of conditions. The reaction run in the presence of a trace of water yielded C6H5SO2F and C1C6H4SO2F. The reaction run in stainless steel at 170°C yielded an amber solid believed to be a polymer with the empirical formula C6H3.67SF2. Chlorination of a C6H5SF3-CSF mixture in monel at 220°C yielded a yellow liquid tentatively identified as a mixture of the new species C6H5SF4C1, FC6H4SF4C1 and C1C6H4SF4C1."],"dc:identifier":["https://digitalcommons.cwu.edu/etd/975"],"dc:language":["English"],"dc:subject":["Science","Chemistry","Sulfur compounds","Physical Sciences and Mathematics"],"dc:title":["Preparation of Phenylsulphur Chloride Tetrafluoride"],"dc:type":["Text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_name":["Master of Science (MS)"]},"updated_at":"2026-07-24T01:37:23Z"}