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ResearchSpace@Auckland

X-ray structural investigations of bromo-oxoditerpenoids and the nickel (II) chelate of a pyridoxal-amino acid intermediate

Abstract

dc:description.abstract

The crystal structure of bis-(pyridoxylidene-L-valine)nickel(II) hydrate (referred to as nickel(II) pyridoxylidene L-valine) has been determined but the difficulty in detecting small deviations from body-centred symmetry, and in locating all solvent molecules, has precluded an accurate analysis. Octahedral coordination to the nickel atom is achieved by the attachment of two Schiff base units. The fused ring system of each unit reveals distortions from planarity.

Degree

thesis:*
Name thesis:degree_name
PhD
Level thesis:degree_level
Doctoral
Discipline thesis:degree_discipline
Chemistry
Grantor dc:publisher
ResearchSpace@Auckland
Year dc:date.issued
1970

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Cutfield, John Franklin
Advisor dc:contributor.advisor
  • Porfessor T. N. Waters

Rights

dc:rights
Statement dc:rights
  • Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
Language dc:language.iso
en

Identifiers

dc:identifier.*
Handle dc:identifier.uri
https://hdl.handle.net/2292/2596
OAI identifier oai:identifier
oai:researchspace.auckland.ac.nz:2292/2596

Chain of custody

source
Harvested from
University of Auckland
Base URL
researchspace.auckland.ac.nz/server/oai/request
Last updated
2026-07-24
Source record
OAI-PMH GetRecord
related terms
citation

Cutfield, John Franklin. X-ray structural investigations of bromo-oxoditerpenoids and the nickel (II) chelate of a pyridoxal-amino acid intermediate. Doctoral thesis, ResearchSpace@Auckland, 1970. https://hdl.handle.net/2292/2596