{"id":{"repo_id":"auckland-ms","oai_identifier":"oai:researchspace.auckland.ac.nz:2292/2596"},"canonical_url":"https://search.dev.ndltd.org/etd/auckland-ms/oai:researchspace.auckland.ac.nz:2292/2596","repository":{"repo_id":"auckland-ms","name":"University of Auckland","base_url":"https://researchspace.auckland.ac.nz/server/oai/request"},"display":{"title":"X-ray structural investigations of bromo-oxoditerpenoids and the nickel (II) chelate of a pyridoxal-amino acid intermediate","abstract":"The crystal structure of bis-(pyridoxylidene-L-valine)nickel(II) hydrate (referred to as nickel(II) pyridoxylidene L-valine) has been determined but the difficulty in detecting small deviations from body-centred symmetry, and in locating all solvent molecules, has precluded an accurate analysis. Octahedral coordination to the nickel atom is achieved by the attachment of two Schiff base units. The fused ring system of each unit reveals distortions from planarity.","abstract_html":"The crystal structure of bis-(pyridoxylidene-L-valine)nickel(II) hydrate (referred to as nickel(II) pyridoxylidene L-valine) has been determined but the difficulty in detecting small deviations from body-centred symmetry, and in locating all solvent molecules, has precluded an accurate analysis. Octahedral coordination to the nickel atom is achieved by the attachment of two Schiff base units. The fused ring system of each unit reveals distortions from planarity.","abstract_has_math":false,"creators":["Cutfield, John Franklin"],"institution":"ResearchSpace@Auckland","degree_name":"PhD","degree_level":"Doctoral","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":[],"advisors":["Porfessor T. N. Waters"],"committee_chairs":[],"committee_members":[],"year":1970,"date_issued":"1970","date_published":"1970","updated_at":"2026-07-24T01:04:15Z","subjects":[],"languages":["en"],"rights":["Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated."],"rights_urls":["https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm"],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2292/2596","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Porfessor T. N. 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Octahedral coordination to the nickel atom is achieved by the attachment of two Schiff base units. The fused ring system of each unit reveals distortions from planarity."]},{"key":"dc:format","label":"Dc Format","values":["Scanned from print thesis"]},{"key":"dc:title","label":"Title","values":["X-ray structural investigations of bromo-oxoditerpenoids and the nickel (II) chelate of a pyridoxal-amino acid intermediate"]}]}],"canonical_facts":{"dc:contributor.advisor":["Porfessor T. N. Waters"],"dc:creator":["Cutfield, John Franklin"],"dc:date.accessioned":["2008-07-11T01:41:03Z"],"dc:date.available":["2008-07-11T01:41:03Z"],"dc:date.issued":["1970"],"dc:description.abstract":["The crystal structure of bis-(pyridoxylidene-L-valine)nickel(II) hydrate (referred to as nickel(II) pyridoxylidene L-valine) has been determined but the difficulty in detecting small deviations from body-centred symmetry, and in locating all solvent molecules, has precluded an accurate analysis. Octahedral coordination to the nickel atom is achieved by the attachment of two Schiff base units. The fused ring system of each unit reveals distortions from planarity."],"dc:format":["Scanned from print thesis"],"dc:identifier.uri":["https://hdl.handle.net/2292/2596"],"dc:language.iso":["en"],"dc:publisher":["ResearchSpace@Auckland"],"dc:relation.isreferencedby":["UoA216114"],"dc:rights":["Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated."],"dc:rights.uri":["https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm"],"dc:title":["X-ray structural investigations of bromo-oxoditerpenoids and the nickel (II) chelate of a pyridoxal-amino acid intermediate"],"dc:type":["Thesis"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Doctoral"],"thesis:degree_name":["PhD"],"thesis:institution_name":["The University of Auckland"]},"updated_at":"2026-07-24T01:04:15Z"}