Structural studies of some copper(II) coordination compounds

The crystal structures of four coordination compounds of copper(II) have been investigated by three-dimensional X-ray methods. The structure of one crystalline form of bis-(N-ethyl-salicylaldiminato) copper(II) has revealed that the copper atom in such a compound may adopt a tetrahedrally-distorted coordination geometry under less severe steric conditions than had previously been supposed. The structures of a methylamine perchlorate adduct of NN’-ethylenebis-(acetylacetoneiminato) copper(II) and p-nitrophenol and chloroform adducts of NN’-ethylenebis-(salicylaldiminato) copper(II) have indicated that the bonding requirements of the copper atom can be modified by hydrogen bonding involving a ligand atom.

Name thesis:degree_name

PhD

Level thesis:degree_level

Doctoral

Discipline thesis:degree_discipline

Chemistry

Grantor dc:publisher

ResearchSpace@Auckland

Year dc:date.issued

1967

Author dc:creator

• Baker, Edward Neill

Advisors dc:contributor.advisor

• Associate Professor T. N. Waters
• Professor D. Hall

Statement dc:rights

• Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Licence dc:rights.uri

• https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm

Language dc:language.iso

en

Handle dc:identifier.uri

https://hdl.handle.net/2292/2594

OAI identifier oai:identifier

oai:researchspace.auckland.ac.nz:2292/2594