{"id":{"repo_id":"auckland-ms","oai_identifier":"oai:researchspace.auckland.ac.nz:2292/2594"},"canonical_url":"https://search.dev.ndltd.org/etd/auckland-ms/oai:researchspace.auckland.ac.nz:2292/2594","repository":{"repo_id":"auckland-ms","name":"University of Auckland","base_url":"https://researchspace.auckland.ac.nz/server/oai/request"},"display":{"title":"Structural studies of some copper(II) coordination compounds","abstract":"The crystal structures of four coordination compounds of copper(II) have been investigated by three-dimensional X-ray methods. The structure of one crystalline form of bis-(N-ethyl-salicylaldiminato) copper(II) has revealed that the copper atom in such a compound may adopt a tetrahedrally-distorted coordination geometry under less severe steric conditions than had previously been supposed. The structures of a methylamine perchlorate adduct of NN’-ethylenebis-(acetylacetoneiminato) copper(II) and p-nitrophenol and chloroform adducts of NN’-ethylenebis-(salicylaldiminato) copper(II) have indicated that the bonding requirements of the copper atom can be modified by hydrogen bonding involving a ligand atom.","abstract_html":"The crystal structures of four coordination compounds of copper(II) have been investigated by three-dimensional X-ray methods. The structure of one crystalline form of bis-(N-ethyl-salicylaldiminato) copper(II) has revealed that the copper atom in such a compound may adopt a tetrahedrally-distorted coordination geometry under less severe steric conditions than had previously been supposed. The structures of a methylamine perchlorate adduct of NN’-ethylenebis-(acetylacetoneiminato) copper(II) and p-nitrophenol and chloroform adducts of NN’-ethylenebis-(salicylaldiminato) copper(II) have indicated that the bonding requirements of the copper atom can be modified by hydrogen bonding involving a ligand atom.","abstract_has_math":false,"creators":["Baker, Edward Neill"],"institution":"ResearchSpace@Auckland","degree_name":"PhD","degree_level":"Doctoral","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":[],"advisors":["Associate Professor T. N. Waters","Professor D. Hall"],"committee_chairs":[],"committee_members":[],"year":1967,"date_issued":"1967","date_published":"1967","updated_at":"2026-07-24T01:04:15Z","subjects":[],"languages":["en"],"rights":["Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated."],"rights_urls":["https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm"],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/2292/2594","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Associate Professor T. N. Waters","Professor D. 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The structure of one crystalline form of bis-(N-ethyl-salicylaldiminato) copper(II) has revealed that the copper atom in such a compound may adopt a tetrahedrally-distorted coordination geometry under less severe steric conditions than had previously been supposed. The structures of a methylamine perchlorate adduct of NN’-ethylenebis-(acetylacetoneiminato) copper(II) and p-nitrophenol and chloroform adducts of NN’-ethylenebis-(salicylaldiminato) copper(II) have indicated that the bonding requirements of the copper atom can be modified by hydrogen bonding involving a ligand atom."]},{"key":"dc:format","label":"Dc Format","values":["Scanned from print thesis"]},{"key":"dc:title","label":"Title","values":["Structural studies of some copper(II) coordination compounds"]}]}],"canonical_facts":{"dc:contributor.advisor":["Associate Professor T. N. Waters","Professor D. Hall"],"dc:creator":["Baker, Edward Neill"],"dc:date.accessioned":["2008-07-09T03:19:51Z"],"dc:date.available":["2008-07-09T03:19:51Z"],"dc:date.issued":["1967"],"dc:description.abstract":["The crystal structures of four coordination compounds of copper(II) have been investigated by three-dimensional X-ray methods. The structure of one crystalline form of bis-(N-ethyl-salicylaldiminato) copper(II) has revealed that the copper atom in such a compound may adopt a tetrahedrally-distorted coordination geometry under less severe steric conditions than had previously been supposed. The structures of a methylamine perchlorate adduct of NN’-ethylenebis-(acetylacetoneiminato) copper(II) and p-nitrophenol and chloroform adducts of NN’-ethylenebis-(salicylaldiminato) copper(II) have indicated that the bonding requirements of the copper atom can be modified by hydrogen bonding involving a ligand atom."],"dc:format":["Scanned from print thesis"],"dc:identifier.uri":["https://hdl.handle.net/2292/2594"],"dc:language.iso":["en"],"dc:publisher":["ResearchSpace@Auckland"],"dc:relation.isreferencedby":["UoA216109"],"dc:rights":["Items in ResearchSpace are protected by copyright, with all rights reserved, unless otherwise indicated."],"dc:rights.uri":["https://researchspace.auckland.ac.nz/docs/uoa-docs/rights.htm"],"dc:title":["Structural studies of some copper(II) coordination compounds"],"dc:type":["Thesis"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Doctoral"],"thesis:degree_name":["PhD"],"thesis:institution_name":["The University of Auckland"]},"updated_at":"2026-07-24T01:04:15Z"}