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University of Illinois at Urbana-Champaign
Synthesis of Heterometallic nitridoruthenium(VI) Complexes With Nickel, Palladium, or Platinum: New Catalysts for the Aerobic Oxidation of Alcohols
Abstract
dc:descriptionThe scope and limitations of [PPh4][Ru(N)Me2(mu-O) 2Pd((-)-sparteine)] as a catalytic aerobic oxidant of organic alcohols is explored. The complex [PPh4][Ru(N)Me2(mu2 -O)2Pd((-)-sparteine)] oxidizes aryl and allyl alcohols to their corresponding aldehydes. The complex also catalytically rearranges allylic alcohols to their corresponding unsaturated aldehydes. The mechanism of oxidation for [PPh4][Ru(N)Me(mu2-O)2Pd((-)-sparteine)] closely mirrors that of the previously described heterobimetallic complex [N(n-Bu4)][Os(N)(CH2SiCH3)2(mu 2-O)2CrO2]. It is first order in complex and first order in benzyl alcohol.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2005
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Kuiper, Jesse Lee
- Contributors dc:contributor
-
- Shapley, Patricia A.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI3199052
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84191