Synthesis of Heterometallic nitridoruthenium(VI) Complexes With Nickel, Palladium, or Platinum: New Catalysts for the Aerobic Oxidation of Alcohols
type: CreativeWork
description: The scope and limitations of [PPh4][Ru(N)Me2(mu-O) 2Pd((-)-sparteine)] as a catalytic aerobic oxidant of organic alcohols is explored. The complex [PPh4][Ru(N)Me2(mu2 -O)2Pd((-)-sparteine)] oxidizes aryl and allyl alcohols to their corresponding aldehydes. The complex also catalytically rearranges allylic alcohols to their corresponding unsaturated aldehydes. The mechanism of oxidation for [PPh4][Ru(N)Me(mu2-O)2Pd((-)-sparteine)] closely mirrors that of the previously described heterobimetallic complex [N(n-Bu4)][Os(N)(CH2SiCH3)2(mu 2-O)2CrO2]. It is first order in complex and first order in benzyl alcohol.
abstract: The scope and limitations of [PPh4][Ru(N)Me2(mu-O) 2Pd((-)-sparteine)] as a catalytic aerobic oxidant of organic alcohols is explored. The complex [PPh4][Ru(N)Me2(mu2 -O)2Pd((-)-sparteine)] oxidizes aryl and allyl alcohols to their corresponding aldehydes. The complex also catalytically rearranges allylic alcohols to their corresponding unsaturated aldehydes. The mechanism of oxidation for [PPh4][Ru(N)Me(mu2-O)2Pd((-)-sparteine)] closely mirrors that of the previously described heterobimetallic complex [N(n-Bu4)][Os(N)(CH2SiCH3)2(mu 2-O)2CrO2]. It is first order in complex and first order in benzyl alcohol.
author: Kuiper, Jesse Lee
language: eng
keywords: Chemistry, Organic
date published: 2005
date modified: 2026-07-22T22:26:22Z
provider: University of Illinois - Urbana-Champaign
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Illinois at Urbana-Champaign

PropertyValue
property ID: Handle
value: http://hdl.handle.net/2142/84191