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University of Illinois at Urbana-Champaign

Kinetics and Mechanisms of Metal Carbonyl Radical Reactions

Abstract

dc:description

Dinuclear metal carbonyl compounds, M(,2)(CO)(,2m)L(,2n), generally possess an intense UV absorption corresponding to a (sigma) (--->) (sigma)* transition of an electron in the metal-metal bond. Irradiation into this absorption results in formation of the (.)M(CO)(,m)L(,n) radicals with high quantum efficiencies.

Degree

thesis:*
Name thesis:degree_name
Ph.D.
Level thesis:degree_level
Dissertation
Discipline thesis:degree_discipline
Chemistry
Grantor
University of Illinois at Urbana-Champaign
Year dc:date
2014

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Wegman, Richard William

Subjects

dc:subject × 1

Rights

Language dc:language
eng

Identifiers

dc:identifier.*
Identifier
(UMI)AAI8114497
OAI identifier oai:identifier
oai:www.ideals.illinois.edu:2142/67269

Chain of custody

source
Harvested from
University of Illinois - Urbana-Champaign
Base URL
www.ideals.illinois.edu/oai-pmh
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Wegman, Richard William. Kinetics and Mechanisms of Metal Carbonyl Radical Reactions. Dissertation thesis, University of Illinois at Urbana-Champaign, 2014. http://hdl.handle.net/2142/67269