Kinetics and Mechanisms of Metal Carbonyl Radical Reactions
type: CreativeWork
description: Dinuclear metal carbonyl compounds, M(,2)(CO)(,2m)L(,2n), generally possess an intense UV absorption corresponding to a (sigma) (--->) (sigma)* transition of an electron in the metal-metal bond. Irradiation into this absorption results in formation of the (.)M(CO)(,m)L(,n) radicals with high quantum efficiencies.
abstract: Dinuclear metal carbonyl compounds, M(,2)(CO)(,2m)L(,2n), generally possess an intense UV absorption corresponding to a (sigma) (--->) (sigma)* transition of an electron in the metal-metal bond. Irradiation into this absorption results in formation of the (.)M(CO)(,m)L(,n) radicals with high quantum efficiencies.
author: Wegman, Richard William
language: eng
keywords: Chemistry, Inorganic
date published: 2014-12-13T20:11:15Z
date modified: 2026-07-22T22:25:57Z
provider: University of Illinois - Urbana-Champaign
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Illinois at Urbana-Champaign

PropertyValue
property ID: Handle
value: http://hdl.handle.net/2142/67269