Properties and Derivatives of Cyclic Sulphur Imides

<p> The methylation of three isomeric hexasulphur diimides under basic conditions has been investigated. Both mono- and dimethylated products have been obtained from the 1, 5- and 1,4-hexasulphur diimides. The anion formed from the 1,3 isomer was found to undergo decomposition, the major products being polysulphides and N-methyl heptasulphur imide. The usefulness of proton NMR, mass spectra, and infrared spectra in conjunction with these compounds has been considered.</p>

Department dc:contributor.department

Chemistry

Year dc:date.issued

1968

Author dc:creator

• Tingle, Edith May

Advisor dc:contributor.advisor

• Olsen, F. P.

• properties, derivatives, cyclic, sulphur, imides

Language dc:language.iso

en_US

Handle dc:identifier.uri

http://hdl.handle.net/11375/20373

OAI record oai:identifier

https://macsphere.mcmaster.ca/server/oai/request?verb=GetRecord&metadataPrefix=dim&identifier=oai%3Amacsphere.mcmaster.ca%3A11375%2F20373