ΟΞΕΙΔΩΤΙΚΕΣ ΑΝΤΙΔΡΑΣΕΙΣ ΣΥΜΠΛΟΚΩΝ ΠΑΛΛΑΔΙΟΥ ΕΠΙ ΟΛΕΦΙΝΩΝ

REACTION OF [PDCL2(OLEFIN)]2 (OLEFIN=CYCLOHEXENE, CYCLOOCTENE, CYCLOHEPTENE) WITH PDO2(PPH3)2 GIVES THE CORRESPONDING KETONES AS PRODUCTS. REACTION OF THE SAME OLEFIN COMPLEXES WITH PDO2(PPH3)2 IN THE PRESENCE OF AND HA(HA=TRIFLUOROACETIC AND OR METHANE SULFONIC AND) GIVES CYCLOHEXENONE AND A MIXTURE OF CYCLOOCTENOLE AND CYCLOOCTANONE FOR CYCLOHEXENE AND CYCLOOCTENE RESPECTIVELY. REACTION OFOLEFINS WITH PDO2(PPH3)2 IN THE PRESENCE OF LEWIS' ACIDS (BF3.EE2O, ALCL3) GIVES LACTONES AND POLYMERIC OXIDATION COMPOUNDS AS PRODUCTS. IMMUNILISATION OF PALLADIUM ON POLYMERS AND REACTION OF OLEFINS UNDER OXIDATIVE CONDITIONS GIVES MAINLY DIMERIZATION PRODUCTS.

Grantor dc:publisher

National and Kapodistrian University of Athens

Year dc:date

1987

Authors dc:creator

• Δανόπουλος, Ανδρέας
• Danopoulos, Andreas

• ΔΙΟΞΥΓΕΝΙΚΑ ΣΥΜΠΛΟΚΑ ΠΑΛΛΑΔΙΟΥ
• ΚΥΚΛΟΕΞΕΝΙΟ
• ΚΥΚΛΟΟΚΤΕΝΙΟ
• ΟΛΕΦΙΝΙΚΑ ΣΥΜΠΛΟΚΑ ΠΑΛΛΑΔΙΟΥ
• ΠΑΛΛΑΔΙΟ ΕΠΙ ΠΟΛΥΜΕΡΩΝ
• CYCLOHEXENE
• CYCLOOCTENE
• IMMOBILIZED PALLADIUM
• PALLADIUM DIOXYGEN COMPLEXES
• PALLADIUM OLEFIN COMPLEXES
• Φυσικές Επιστήμες
• Χημεία
• Natural Sciences
• Chemical Sciences

Language dc:language

gre

Identifier

10.12681/eadd/0559

OAI identifier oai:identifier

oai:10442/0559