{"id":{"repo_id":"greece","oai_identifier":"oai:10442/0559"},"canonical_url":"https://search.dev.ndltd.org/etd/greece/oai:10442/0559","repository":{"repo_id":"greece","name":"Greek National Archive of PhD Theses","base_url":"https://phdtheses.ekt.gr/eadd_oai/request"},"display":{"title":"ΟΞΕΙΔΩΤΙΚΕΣ ΑΝΤΙΔΡΑΣΕΙΣ ΣΥΜΠΛΟΚΩΝ ΠΑΛΛΑΔΙΟΥ ΕΠΙ ΟΛΕΦΙΝΩΝ","abstract":"REACTION OF [PDCL2(OLEFIN)]2 (OLEFIN=CYCLOHEXENE, CYCLOOCTENE, CYCLOHEPTENE) WITH PDO2(PPH3)2 GIVES THE CORRESPONDING KETONES AS PRODUCTS. REACTION OF THE SAME OLEFIN COMPLEXES WITH PDO2(PPH3)2 IN THE PRESENCE OF AND HA(HA=TRIFLUOROACETIC AND OR METHANE SULFONIC AND) GIVES CYCLOHEXENONE AND A MIXTURE OF CYCLOOCTENOLE AND CYCLOOCTANONE FOR CYCLOHEXENE AND CYCLOOCTENE RESPECTIVELY. REACTION OFOLEFINS WITH PDO2(PPH3)2 IN THE PRESENCE OF LEWIS' ACIDS (BF3.EE2O, ALCL3) GIVES LACTONES AND POLYMERIC OXIDATION COMPOUNDS AS PRODUCTS. IMMUNILISATION OF PALLADIUM ON POLYMERS AND REACTION OF OLEFINS UNDER OXIDATIVE CONDITIONS GIVES MAINLY DIMERIZATION PRODUCTS.","abstract_html":"REACTION OF [PDCL2(OLEFIN)]2 (OLEFIN=CYCLOHEXENE, CYCLOOCTENE, CYCLOHEPTENE) WITH PDO2(PPH3)2 GIVES THE CORRESPONDING KETONES AS PRODUCTS. REACTION OF THE SAME OLEFIN COMPLEXES WITH PDO2(PPH3)2 IN THE PRESENCE OF AND HA(HA=TRIFLUOROACETIC AND OR METHANE SULFONIC AND) GIVES CYCLOHEXENONE AND A MIXTURE OF CYCLOOCTENOLE AND CYCLOOCTANONE FOR CYCLOHEXENE AND CYCLOOCTENE RESPECTIVELY. REACTION OFOLEFINS WITH PDO2(PPH3)2 IN THE PRESENCE OF LEWIS' ACIDS (BF3.EE2O, ALCL3) GIVES LACTONES AND POLYMERIC OXIDATION COMPOUNDS AS PRODUCTS. IMMUNILISATION OF PALLADIUM ON POLYMERS AND REACTION OF OLEFINS UNDER OXIDATIVE CONDITIONS GIVES MAINLY DIMERIZATION PRODUCTS.","abstract_has_math":false,"creators":["Δανόπουλος, Ανδρέας","Danopoulos, Andreas"],"institution":"National and Kapodistrian University of Athens","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1987,"date_issued":"1987","date_published":"1987","updated_at":"2026-07-24T02:25:21Z","subjects":["ΔΙΟΞΥΓΕΝΙΚΑ ΣΥΜΠΛΟΚΑ ΠΑΛΛΑΔΙΟΥ","ΚΥΚΛΟΕΞΕΝΙΟ","ΚΥΚΛΟΟΚΤΕΝΙΟ","ΟΛΕΦΙΝΙΚΑ ΣΥΜΠΛΟΚΑ ΠΑΛΛΑΔΙΟΥ","ΠΑΛΛΑΔΙΟ ΕΠΙ ΠΟΛΥΜΕΡΩΝ","CYCLOHEXENE","CYCLOOCTENE","IMMOBILIZED PALLADIUM","PALLADIUM DIOXYGEN COMPLEXES","PALLADIUM OLEFIN COMPLEXES","Φυσικές Επιστήμες","Χημεία","Natural Sciences","Chemical Sciences"],"languages":["gre"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/0559"],"render_values":[{"text":"10.12681/eadd/0559","href":"https://doi.org/10.12681/eadd/0559","code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/10442/hedi/0559","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:creator","label":"Author","values":["Δανόπουλος, Ανδρέας","Danopoulos, Andreas"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["1987"]},{"key":"dc:publisher","label":"Institution","values":["National and Kapodistrian University of Athens","Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)"]},{"key":"dc:type","label":"Dc Type","values":["PhD Thesis"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["ΔΙΟΞΥΓΕΝΙΚΑ ΣΥΜΠΛΟΚΑ ΠΑΛΛΑΔΙΟΥ","ΚΥΚΛΟΕΞΕΝΙΟ","ΚΥΚΛΟΟΚΤΕΝΙΟ","ΟΛΕΦΙΝΙΚΑ ΣΥΜΠΛΟΚΑ ΠΑΛΛΑΔΙΟΥ","ΠΑΛΛΑΔΙΟ ΕΠΙ ΠΟΛΥΜΕΡΩΝ","CYCLOHEXENE","CYCLOOCTENE","IMMOBILIZED PALLADIUM","PALLADIUM DIOXYGEN COMPLEXES","PALLADIUM OLEFIN COMPLEXES","Φυσικές Επιστήμες","Χημεία","Natural Sciences","Chemical Sciences"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["gre"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["10.12681/eadd/0559","http://hdl.handle.net/10442/hedi/0559"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["REACTION OF [PDCL2(OLEFIN)]2 (OLEFIN=CYCLOHEXENE, CYCLOOCTENE, CYCLOHEPTENE) WITH PDO2(PPH3)2 GIVES THE CORRESPONDING KETONES AS PRODUCTS. REACTION OF THE SAME OLEFIN COMPLEXES WITH PDO2(PPH3)2 IN THE PRESENCE OF AND HA(HA=TRIFLUOROACETIC AND OR METHANE SULFONIC AND) GIVES CYCLOHEXENONE AND A MIXTURE OF CYCLOOCTENOLE AND CYCLOOCTANONE FOR CYCLOHEXENE AND CYCLOOCTENE RESPECTIVELY. REACTION OFOLEFINS WITH PDO2(PPH3)2 IN THE PRESENCE OF LEWIS' ACIDS (BF3.EE2O, ALCL3) GIVES LACTONES AND POLYMERIC OXIDATION COMPOUNDS AS PRODUCTS. IMMUNILISATION OF PALLADIUM ON POLYMERS AND REACTION OF OLEFINS UNDER OXIDATIVE CONDITIONS GIVES MAINLY DIMERIZATION PRODUCTS.","ΑΝΤΙΔΡΑΣΗ ΤΩΝ ΣΥΜΠΛΟΚΩΝ [PDCL2(ΟΛΕΦΙΝΗ)]2 (ΟΛΕΦΙΝΗ=ΚΥΚΛΟΕΞΕΝΙΟ, ΚΥΚΛΟΣΙΑΤΕΝΙΟ, ΚΥΚΛΟΟΚΤΑΝΙΟ) ΜΕ PDO2(PPH3)2 ΔΙΔΕΙ ΩΣ ΠΡΟΙΟΝΤΑ ΤΙΣ ΑΝΤΙΣΤΟΙΧΕΣ ΚΕΤΟΝΕΣ. ΑΝΤΙΔΡΑΣΗ ΤΩΝ ΑΝΩΤΕΡΩ ΟΛΑΦΙΝΙΚΩΝ ΣΥΜΠΛΟΚΩΝ ΜΕ PDO2(PPH3)2 ΠΑΡΟΥΣΙΑ ΟΞΕΟΣ ΗΑ(ΗΑ=ΤΡΙΦΘΟΡΟ-ΟΞΕΙΚΟ 'Η ΜΕΘΟΝΟΣΟΥΛΦΟΝΙΚΟ ΟΞΥ) ΔΙΔΕΙ ΚΥΚΛΟΕΞΕΝΟΝΗ ΚΑΙ ΜΙΓΜΑ ΚΥΚΛΟΟΚΤΕΝΟΛΗΣ ΚΑΙ ΚΥΚΛΟΟΚΤΑΝΟΝΗΣ ΟΤΑΝ ΧΡΗΣΙΜΟΠΟΙΕΙΤΑΙ ΚΥΚΛΟΕΞΕΝΙΟ ΚΑΙ ΚΥΚΛΟΟΚΤΕΝΙΟ ΑΝΤΙΣΤΟΙΧΑ.ΑΝΤΙΔΡΑΣΗ ΟΛΕΦΙΝΗΣ ΜΕ PDO2(PPH3)2 ΠΑΡΟΥΣΙΑ ΟΞΕΩΝ LEWIS (BF3.EE2O, ALCL3) ΔΙΔΕΙΛΑΚΤΟΝΕΣ ΚΑΙ ΠΟΛΥΜΕΡΗ ΟΞΕΙΔΩΜΕΝΑ ΠΡΟΙΟΝΤΑ. ΑΚΙΝΗΤΟΠΟΙΗΣΗ ΤΟΥ ΠΑΛΛΑΔΙΟΥ ΕΠΙ ΠΟΛΥΜΕΡΟΥΣ ΚΑΙ ΑΝΤΙΔΡΑΣΗ ΜΕ ΟΛΕΦΙΝΕΣ ΚΑΙ ΟΞΕΙΔΩΤΙΚΕΣ ΣΥΝΘΗΚΕΣ ΔΙΔΕΙ ΚΥΡΙΩΣ ΠΡΟΙΟΝΤΑ ΔΙΜΕΡΙΣΜΟΥ."]},{"key":"dc:title","label":"Title","values":["ΟΞΕΙΔΩΤΙΚΕΣ ΑΝΤΙΔΡΑΣΕΙΣ ΣΥΜΠΛΟΚΩΝ ΠΑΛΛΑΔΙΟΥ ΕΠΙ ΟΛΕΦΙΝΩΝ","OXIDATIVE REACTIONS OF OLEFINS USING PALLADIUM COMPLEXES"]}]}],"canonical_facts":{"dc:creator":["Δανόπουλος, Ανδρέας","Danopoulos, Andreas"],"dc:date":["1987"],"dc:description":["REACTION OF [PDCL2(OLEFIN)]2 (OLEFIN=CYCLOHEXENE, CYCLOOCTENE, CYCLOHEPTENE) WITH PDO2(PPH3)2 GIVES THE CORRESPONDING KETONES AS PRODUCTS. REACTION OF THE SAME OLEFIN COMPLEXES WITH PDO2(PPH3)2 IN THE PRESENCE OF AND HA(HA=TRIFLUOROACETIC AND OR METHANE SULFONIC AND) GIVES CYCLOHEXENONE AND A MIXTURE OF CYCLOOCTENOLE AND CYCLOOCTANONE FOR CYCLOHEXENE AND CYCLOOCTENE RESPECTIVELY. REACTION OFOLEFINS WITH PDO2(PPH3)2 IN THE PRESENCE OF LEWIS' ACIDS (BF3.EE2O, ALCL3) GIVES LACTONES AND POLYMERIC OXIDATION COMPOUNDS AS PRODUCTS. IMMUNILISATION OF PALLADIUM ON POLYMERS AND REACTION OF OLEFINS UNDER OXIDATIVE CONDITIONS GIVES MAINLY DIMERIZATION PRODUCTS.","ΑΝΤΙΔΡΑΣΗ ΤΩΝ ΣΥΜΠΛΟΚΩΝ [PDCL2(ΟΛΕΦΙΝΗ)]2 (ΟΛΕΦΙΝΗ=ΚΥΚΛΟΕΞΕΝΙΟ, ΚΥΚΛΟΣΙΑΤΕΝΙΟ, ΚΥΚΛΟΟΚΤΑΝΙΟ) ΜΕ PDO2(PPH3)2 ΔΙΔΕΙ ΩΣ ΠΡΟΙΟΝΤΑ ΤΙΣ ΑΝΤΙΣΤΟΙΧΕΣ ΚΕΤΟΝΕΣ. ΑΝΤΙΔΡΑΣΗ ΤΩΝ ΑΝΩΤΕΡΩ ΟΛΑΦΙΝΙΚΩΝ ΣΥΜΠΛΟΚΩΝ ΜΕ PDO2(PPH3)2 ΠΑΡΟΥΣΙΑ ΟΞΕΟΣ ΗΑ(ΗΑ=ΤΡΙΦΘΟΡΟ-ΟΞΕΙΚΟ 'Η ΜΕΘΟΝΟΣΟΥΛΦΟΝΙΚΟ ΟΞΥ) ΔΙΔΕΙ ΚΥΚΛΟΕΞΕΝΟΝΗ ΚΑΙ ΜΙΓΜΑ ΚΥΚΛΟΟΚΤΕΝΟΛΗΣ ΚΑΙ ΚΥΚΛΟΟΚΤΑΝΟΝΗΣ ΟΤΑΝ ΧΡΗΣΙΜΟΠΟΙΕΙΤΑΙ ΚΥΚΛΟΕΞΕΝΙΟ ΚΑΙ ΚΥΚΛΟΟΚΤΕΝΙΟ ΑΝΤΙΣΤΟΙΧΑ.ΑΝΤΙΔΡΑΣΗ ΟΛΕΦΙΝΗΣ ΜΕ PDO2(PPH3)2 ΠΑΡΟΥΣΙΑ ΟΞΕΩΝ LEWIS (BF3.EE2O, ALCL3) ΔΙΔΕΙΛΑΚΤΟΝΕΣ ΚΑΙ ΠΟΛΥΜΕΡΗ ΟΞΕΙΔΩΜΕΝΑ ΠΡΟΙΟΝΤΑ. ΑΚΙΝΗΤΟΠΟΙΗΣΗ ΤΟΥ ΠΑΛΛΑΔΙΟΥ ΕΠΙ ΠΟΛΥΜΕΡΟΥΣ ΚΑΙ ΑΝΤΙΔΡΑΣΗ ΜΕ ΟΛΕΦΙΝΕΣ ΚΑΙ ΟΞΕΙΔΩΤΙΚΕΣ ΣΥΝΘΗΚΕΣ ΔΙΔΕΙ ΚΥΡΙΩΣ ΠΡΟΙΟΝΤΑ ΔΙΜΕΡΙΣΜΟΥ."],"dc:identifier":["10.12681/eadd/0559","http://hdl.handle.net/10442/hedi/0559"],"dc:language":["gre"],"dc:publisher":["National and Kapodistrian University of Athens","Εθνικό και Καποδιστριακό Πανεπιστήμιο Αθηνών (ΕΚΠΑ)"],"dc:subject":["ΔΙΟΞΥΓΕΝΙΚΑ ΣΥΜΠΛΟΚΑ ΠΑΛΛΑΔΙΟΥ","ΚΥΚΛΟΕΞΕΝΙΟ","ΚΥΚΛΟΟΚΤΕΝΙΟ","ΟΛΕΦΙΝΙΚΑ ΣΥΜΠΛΟΚΑ ΠΑΛΛΑΔΙΟΥ","ΠΑΛΛΑΔΙΟ ΕΠΙ ΠΟΛΥΜΕΡΩΝ","CYCLOHEXENE","CYCLOOCTENE","IMMOBILIZED PALLADIUM","PALLADIUM DIOXYGEN COMPLEXES","PALLADIUM OLEFIN COMPLEXES","Φυσικές Επιστήμες","Χημεία","Natural Sciences","Chemical Sciences"],"dc:title":["ΟΞΕΙΔΩΤΙΚΕΣ ΑΝΤΙΔΡΑΣΕΙΣ ΣΥΜΠΛΟΚΩΝ ΠΑΛΛΑΔΙΟΥ ΕΠΙ ΟΛΕΦΙΝΩΝ","OXIDATIVE REACTIONS OF OLEFINS USING PALLADIUM COMPLEXES"],"dc:type":["PhD Thesis"]},"updated_at":"2026-07-24T02:25:21Z"}