Growth and Characterisation of Spray Pyrolytic Doped Zinc and Aluminium Oxide Spectral-Selective thin Films
type: CreativeWork
description: Metal oxide thin films have been used in thin film solar cells and other solar energy applications for many years. The main concern has been to improve their physical, electrical and optical properties in order to increase their efficiency and lower their production costs. Zinc oxide doped with aluminium (ZnO:Al) and aluminium oxide doped with zinc (Al2O3:Zn) thin films have been produced by a spray pyrolysis process onto standard microscope glass slides at different substrate temperatures and for different solution concentrations, spray times and pressure. The main objective was to produce single, double and triple layer thin films and characterized them for their optical, electrical and structural properties. The spectral selectiveness of these oxide thin films and their applicability in producing efficient solar cells has been investigated. Optical measurements in the ultraviolet, visible and near infrared ranges have been performed using the Perkin-Elmer Lambda 19 spectrophotometer. Further optical characterization in the far infrared has been performed using the BX Fourier Transform Infrared (FT-IR) spectrophotometer at the University of Dar es Salaam Solar Energy Research Laboratory. Structural characterization for determination of surface morphology and film thickness has been done using the Atomic Force Microscope and the Tencor Alpha Step IQ Profiler. On the other hand electrical properties have been investigated using the four-point resistance square probe. The transmittance, reflectance and thickness of the thin films as well as the sheet resistance have been experimentally obtained. The solar transmittance of 88 percent has been achieved for Al-doped zinc oxide (ZnO) films whereas 71.94 per cent has been obtained for Zn-doped aluminium oxide (Al2O3). The film thicknesses fall in the range 0.14 - 87.7 μm. The films have low reflectance in the order of 10 percent. Peak reflectance of 25 per cent has been recorded for the wavelength range 8-12 m. The wavele…
abstract: Metal oxide thin films have been used in thin film solar cells and other solar energy applications for many years. The main concern has been to improve their physical, electrical and optical properties in order to increase their efficiency and lower their production costs. Zinc oxide doped with aluminium (ZnO:Al) and aluminium oxide doped with zinc (Al2O3:Zn) thin films have been produced by a spray pyrolysis process onto standard microscope glass slides at different substrate temperatures and for different solution concentrations, spray times and pressure. The main objective was to produce single, double and triple layer thin films and characterized them for their optical, electrical and structural properties. The spectral selectiveness of these oxide thin films and their applicability in producing efficient solar cells has been investigated. Optical measurements in the ultraviolet, visible and near infrared ranges have been performed using the Perkin-Elmer Lambda 19 spectrophotometer. Further optical characterization in the far infrared has been performed using the BX Fourier Transform Infrared (FT-IR) spectrophotometer at the University of Dar es Salaam Solar Energy Research Laboratory. Structural characterization for determination of surface morphology and film thickness has been done using the Atomic Force Microscope and the Tencor Alpha Step IQ Profiler. On the other hand electrical properties have been investigated using the four-point resistance square probe. The transmittance, reflectance and thickness of the thin films as well as the sheet resistance have been experimentally obtained. The solar transmittance of 88 percent has been achieved for Al-doped zinc oxide (ZnO) films whereas 71.94 per cent has been obtained for Zn-doped aluminium oxide (Al2O3). The film thicknesses fall in the range 0.14 - 87.7 μm. The films have low reflectance in the order of 10 percent. Peak reflectance of 25 per cent has been recorded for the wavelength range 8-12 m. The wavele…
author: Simpemba, Prospery C.
language: en
keywords: Thin Films--coatings, Thin Films(metal oxide)--Mechanical properties
date published: 2012-05-02
date modified: 2026-07-27T22:07:08Z
provider: University of Zimbabwe
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Zimbabwe