{"id":{"repo_id":"wustl","oai_identifier":"oai:openscholarship.wustl.edu:etd-1164"},"canonical_url":"https://search.dev.ndltd.org/etd/wustl/oai:openscholarship.wustl.edu:etd-1164","repository":{"repo_id":"wustl","name":"Washington University in St. Louis","base_url":"https://openscholarship.wustl.edu/do/oai/"},"display":{"title":"NMR Search for Mobile, Aluminum-bearing Species during Reactions of Sodium Alanate","abstract":"NaAlH4 has become the archetypal complex: ionic-covalent) hydrogen storage solid, since the discovery in 1997 that titanium and some other metals catalyze the reaction in both directions. Given that spatially separated NaH and Al under excess H2 pressure can form NaAlH4, we have hypothesized a mobile Al- or Na- bearing intermediate species in the reaction scheme. 27Al in situ NMR has been used to discover such a new species during dehydriding of NaAlH4. Importantly, the new species can also be formed under excess H2 pressure without net evolution of Al and H2; the new species can be returned to ambient for further study. The features of the new species include: a very rapid 27Al T1, a sharp line: without MAS) at 300 K that broadens by -60oC, an accompanying sharp hydrogen NMR line that is also motionally narrowed, CPMAS evidence of bonded or at least nearby H, and a 27Al shift just above NaAlH4. The new species appears to be a highly defective form of NaAlH4, where the large concentration of vacancies promotes rapid diffusion of Al and H.","abstract_html":"NaAlH<sub>4<sub> has become the archetypal complex: ionic-covalent) hydrogen storage solid, since the discovery in 1997 that titanium and some other metals catalyze the reaction in both directions. Given that spatially separated NaH and Al under excess H<sub>2<sub> pressure can form NaAlH<sub>4<sub>, we have hypothesized a mobile Al- or Na- bearing intermediate species in the reaction scheme. <super>27<super>Al <italic>in situ<italic> NMR has been used to discover such a new species during dehydriding of NaAlH<sub>4<sub>. Importantly, the new species can also be formed under excess H<sub>2<sub> pressure without net evolution of Al and H<sub>2<sub>; the new species can be returned to ambient for further study. The features of the new species include: a very rapid <super>27<super>Al T<sub>1<sub>, a sharp line: without MAS) at 300 K that broadens by -60<super>o<super>C, an accompanying sharp hydrogen NMR line that is also motionally narrowed, CPMAS evidence of bonded or at least nearby H, and a <super>27<super>Al shift just above NaAlH<sub>4<sub>. The new species appears to be a highly defective form of NaAlH<sub>4<sub>, where the large concentration of vacancies promotes rapid diffusion of Al and H.","abstract_has_math":false,"creators":["Ivancic, Timothy"],"institution":null,"degree_name":"Doctor of Philosophy (PhD)","degree_level":"Dissertation","degree_discipline":"Physics","degree_department":null,"school":null,"contributors":["Mark Conradi"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2010,"date_issued":"2010-01-01T08:00:00Z","date_published":"2010-01-01T08:00:00Z","updated_at":"2026-07-24T06:12:41Z","subjects":["Physics","Condensed Matter","hydrogen storage","in situ 27Al NMR","intermediate species","mobile species","sodium alanate","vacancies"],"languages":["English (en)"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier.doi","label":"DOI","values":["https://doi.org/10.7936/K7W37TFR"],"render_values":[{"text":"https://doi.org/10.7936/K7W37TFR","href":"https://doi.org/10.7936/K7W37TFR","code":true}]}]},"links":{"outbound_url":"https://openscholarship.wustl.edu/etd/165","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Mark Conradi"]},{"key":"dc:creator","label":"Author","values":["Ivancic, Timothy"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.available","label":"Dc Date Available","values":["2010-01-01T08:00:00Z"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Physics"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Doctor of Philosophy (PhD)"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Physics","Condensed Matter","hydrogen storage","in situ 27Al NMR","intermediate species","mobile species","sodium alanate","vacancies"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["English (en)"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://openscholarship.wustl.edu/etd/165"]},{"key":"dc:identifier.doi","label":"DOI","values":["https://doi.org/10.7936/K7W37TFR"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["NaAlH4 has become the archetypal complex: ionic-covalent) hydrogen storage solid, since the discovery in 1997 that titanium and some other metals catalyze the reaction in both directions. Given that spatially separated NaH and Al under excess H2 pressure can form NaAlH4, we have hypothesized a mobile Al- or Na- bearing intermediate species in the reaction scheme. 27Al in situ NMR has been used to discover such a new species during dehydriding of NaAlH4. Importantly, the new species can also be formed under excess H2 pressure without net evolution of Al and H2; the new species can be returned to ambient for further study. The features of the new species include: a very rapid 27Al T1, a sharp line: without MAS) at 300 K that broadens by -60oC, an accompanying sharp hydrogen NMR line that is also motionally narrowed, CPMAS evidence of bonded or at least nearby H, and a 27Al shift just above NaAlH4. The new species appears to be a highly defective form of NaAlH4, where the large concentration of vacancies promotes rapid diffusion of Al and H."]},{"key":"dc:title","label":"Title","values":["NMR Search for Mobile, Aluminum-bearing Species during Reactions of Sodium Alanate"]}]}],"canonical_facts":{"dc:contributor":["Mark Conradi"],"dc:creator":["Ivancic, Timothy"],"dc:date.available":["2010-01-01T08:00:00Z"],"dc:description.abstract":["NaAlH4 has become the archetypal complex: ionic-covalent) hydrogen storage solid, since the discovery in 1997 that titanium and some other metals catalyze the reaction in both directions. Given that spatially separated NaH and Al under excess H2 pressure can form NaAlH4, we have hypothesized a mobile Al- or Na- bearing intermediate species in the reaction scheme. 27Al in situ NMR has been used to discover such a new species during dehydriding of NaAlH4. Importantly, the new species can also be formed under excess H2 pressure without net evolution of Al and H2; the new species can be returned to ambient for further study. The features of the new species include: a very rapid 27Al T1, a sharp line: without MAS) at 300 K that broadens by -60oC, an accompanying sharp hydrogen NMR line that is also motionally narrowed, CPMAS evidence of bonded or at least nearby H, and a 27Al shift just above NaAlH4. The new species appears to be a highly defective form of NaAlH4, where the large concentration of vacancies promotes rapid diffusion of Al and H."],"dc:identifier":["https://openscholarship.wustl.edu/etd/165"],"dc:identifier.doi":["https://doi.org/10.7936/K7W37TFR"],"dc:language":["English (en)"],"dc:subject":["Physics","Condensed Matter","hydrogen storage","in situ 27Al NMR","intermediate species","mobile species","sodium alanate","vacancies"],"dc:title":["NMR Search for Mobile, Aluminum-bearing Species during Reactions of Sodium Alanate"],"thesis:degree_discipline":["Physics"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Doctor of Philosophy (PhD)"]},"updated_at":"2026-07-24T06:12:41Z"}