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Washington University in St. Louis

Nucleation Dynamics for Water Condensation on Hydrophobic Surfaces in the Presence of Non-Condensable Gases

Abstract

dc:description.abstract

The density and rate of nucleation (here-in called nucleation density rate) significantly influences the heat transfer performance during dropwise condensation, as more than 70% of the total heat transfer happen for droplets smaller than 10 μm. Based on the classical nucleation theory, supersaturation strongly influences nucleation dynamics. However, the presence of non-condensable gas can strongly reduce the nucleation density rate by forming a vapor-depleted gas diffusion layer. Therefore, this work studied the relationship between nucleation density rate and supersaturation ratio during dropwise condensation on subcooled smooth hydrophobic surfaces with the presence of non-condensable gases in a custom-built condensation chamber. High-speed imaging and high-resolution microscopy enabled the experimental quantification of condensation dynamics. These were then compared to theoretical values based on the classical nucleation density. Based on the present experiments and a size distribution model, the relationship between heat transfer rate and supersaturation ratio were analyzed. Finally, through experimental observations, it is shown that the fast movement of relatively larger droplets can disturb the diffusion layer and enhance the nucleation density rate.

Degree

thesis:*
Name thesis:degree_name
Master of Science (MS)
Level thesis:degree_level
Thesis
Discipline thesis:degree_discipline
Mechanical Engineering & Materials Science
Year dc:date.available
2020

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Jiang, Xinyu
Contributors dc:contributor
  • Patricia Weisensee
  • David Peters, Ramesh Agarwal

Subjects

dc:subject × 4

Rights

dc:rights
Statement dc:rights
  • I have not registered my thesis with the U.S. Copyright Office, but intend to later.
Language dc:language
English (en)

Identifiers

dc:identifier.*
OAI identifier oai:identifier
oai:openscholarship.wustl.edu:eng_etds-1557

Chain of custody

source
Harvested from
Washington University in St. Louis
Base URL
openscholarship.wustl.edu/do/oai/
Last updated
2026-07-24
Source record
OAI-PMH GetRecord
citation

Jiang, Xinyu. Nucleation Dynamics for Water Condensation on Hydrophobic Surfaces in the Presence of Non-Condensable Gases. Thesis thesis, 2020. https://doi.org/10.7936/d20r-ey56