{"id":{"repo_id":"wurz-thes","oai_identifier":"oai:opus.bibliothek.uni-wuerzburg.de:1047"},"canonical_url":"https://search.dev.ndltd.org/etd/wurz-thes/oai:opus.bibliothek.uni-wuerzburg.de:1047","repository":{"repo_id":"wurz-thes","name":"Universität Wüzburg","base_url":"https://opus.bibliothek.uni-wuerzburg.de/oai"},"display":{"title":"Di(benzothiazol-2-yl)phosphane - Studies on a Janus Head Ligand -","abstract":"The design of ligands is one of the most important and simultaneously challenging fields of research in modern inorganic chemistry. The aim is to synthesise ligands that can serve as coordination units for a broad variety of metal fragments and different purposes. The ligands have to be very flexible concerning their donating behaviour and geometrical prerequisites in order to correspond to the required metal fragments.","abstract_html":"The design of ligands is one of the most important and simultaneously challenging fields of research in modern inorganic chemistry. The aim is to synthesise ligands that can serve as coordination units for a broad variety of metal fragments and different purposes. The ligands have to be very flexible concerning their donating behaviour and geometrical prerequisites in order to correspond to the required metal fragments.","abstract_has_math":false,"creators":["Stey, Thomas Josef"],"institution":"Universität Würzburg","degree_name":null,"degree_level":"thesis.doctoral","degree_discipline":null,"degree_department":null,"school":null,"contributors":["Stalke, Dietmar"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2005,"date_issued":"2005-01-28","date_published":"2005-01-28","updated_at":"2026-07-24T06:11:34Z","subjects":["Phosphanliganden","Ligandendesign","Januskopfligand","Koordinationschemie","Phosphaneligands","Liganddesign","Janus Head Ligand","koordination chemistry"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://opus.bibliothek.uni-wuerzburg.de/frontdoor/index/index/docId/1047","outbound_label":"Repository record","outbound_source":"source_url"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Stalke, Dietmar"]},{"key":"dc:creator","label":"Author","values":["Stey, Thomas Josef"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:publisher","label":"Institution","values":["Universität Würzburg"]},{"key":"dc:type","label":"Dc Type","values":["doctoralThesis"]},{"key":"thesis:degree_level","label":"Degree Level","values":["thesis.doctoral"]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["Universität Würzburg"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Phosphanliganden","Ligandendesign","Januskopfligand","Koordinationschemie","Phosphaneligands","Liganddesign","Janus Head Ligand","koordination chemistry"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["The design of ligands is one of the most important and simultaneously challenging fields of research in modern inorganic chemistry. The aim is to synthesise ligands that can serve as coordination units for a broad variety of metal fragments and different purposes. The ligands have to be very flexible concerning their donating behaviour and geometrical prerequisites in order to correspond to the required metal fragments.","Ziel der vorliegenden Arbeit war die Synthese eines Januskopfliganden der zweiten Generation und die Untersuchung seiner Reaktivität und seines Koordinationsverhalten. Als Zielverbindung wurde Di(benzothiazol-2-yl)phosphan (1) gewählt (Schema 7.1). Neben harten Koordinationsstellen enthalten die heteroaromatischen Substituenten dieses Liganden zusätzlich weiche, die das System im Vergleich zu z. B. Di(pyrid-2-yl)phosphan im Bezug auf mögliche koordinierte Metallfragmente flexibler machen sollten."]},{"key":"dc:format.medium","label":"Dc Format Medium","values":["application/pdf"]},{"key":"dc:title","label":"Title","values":["Di(benzothiazol-2-yl)phosphane - Studies on a Janus Head Ligand -","Di(benzothiazol-2-yl)phosphan - Arbeiten über einen janusköpfigen Liganden -"]}]}],"canonical_facts":{"dc:contributor":["Stalke, Dietmar"],"dc:creator":["Stey, Thomas Josef"],"dc:description.abstract":["The design of ligands is one of the most important and simultaneously challenging fields of research in modern inorganic chemistry. The aim is to synthesise ligands that can serve as coordination units for a broad variety of metal fragments and different purposes. The ligands have to be very flexible concerning their donating behaviour and geometrical prerequisites in order to correspond to the required metal fragments.","Ziel der vorliegenden Arbeit war die Synthese eines Januskopfliganden der zweiten Generation und die Untersuchung seiner Reaktivität und seines Koordinationsverhalten. Als Zielverbindung wurde Di(benzothiazol-2-yl)phosphan (1) gewählt (Schema 7.1). Neben harten Koordinationsstellen enthalten die heteroaromatischen Substituenten dieses Liganden zusätzlich weiche, die das System im Vergleich zu z. B. Di(pyrid-2-yl)phosphan im Bezug auf mögliche koordinierte Metallfragmente flexibler machen sollten."],"dc:format.medium":["application/pdf"],"dc:publisher":["Universität Würzburg"],"dc:subject":["Phosphanliganden","Ligandendesign","Januskopfligand","Koordinationschemie","Phosphaneligands","Liganddesign","Janus Head Ligand","koordination chemistry"],"dc:title":["Di(benzothiazol-2-yl)phosphane - Studies on a Janus Head Ligand -","Di(benzothiazol-2-yl)phosphan - Arbeiten über einen janusköpfigen Liganden -"],"dc:type":["doctoralThesis"],"thesis:degree_level":["thesis.doctoral"],"thesis:institution_name":["Universität Würzburg"]},"updated_at":"2026-07-24T06:11:34Z"}