The cyclohexadiene porition of 1-tertiarybutyl-1, 4-dihydronaphthalene exists in a puckered rather than planar conformation at room temperature, with approximately equal populations of the isomer with the t-butyl group “axial” and “equatorial.” Analysis of chemical shifts and coupling constants was aided by use of a LAOCOON III program.
","abstract_html":"<p>The cyclohexadiene porition of 1-tertiarybutyl-1, 4-dihydronaphthalene exists in a puckered rather than planar conformation at room temperature, with approximately equal populations of the isomer with the t-butyl group “axial” and “equatorial.” Analysis of chemical shifts and coupling constants was aided by use of a LAOCOON III program. </p>","abstract_has_math":false,"creators":["Huang, Su-Jen"],"institution":null,"degree_name":"Master of Science","degree_level":null,"degree_discipline":"Department of Chemistry","degree_department":null,"school":null,"contributors":["Norman Holy"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":1977,"date_issued":"1977-02-01T08:00:00Z","date_published":"1977-02-01T08:00:00Z","updated_at":"2026-07-24T06:08:39Z","subjects":["Chemistry"],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"https://digitalcommons.wku.edu/theses/1425","outbound_label":"Repository record","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Norman Holy"]},{"key":"dc:creator","label":"Author","values":["Huang, Su-Jen"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:type","label":"Dc Type","values":["Thesis"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Department of Chemistry"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Master of Science"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["https://digitalcommons.wku.edu/theses/1425"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["The cyclohexadiene porition of 1-tertiarybutyl-1, 4-dihydronaphthalene exists in a puckered rather than planar conformation at room temperature, with approximately equal populations of the isomer with the t-butyl group “axial” and “equatorial.” Analysis of chemical shifts and coupling constants was aided by use of a LAOCOON III program.
"]},{"key":"dc:title","label":"Title","values":["Conformational Analysis of 1-Tertiarybutyl-1, 4-Dihydronaphthalene a Turnover from SRNI to SNI Mechanism"]}]}],"canonical_facts":{"dc:contributor":["Norman Holy"],"dc:creator":["Huang, Su-Jen"],"dc:description.abstract":["The cyclohexadiene porition of 1-tertiarybutyl-1, 4-dihydronaphthalene exists in a puckered rather than planar conformation at room temperature, with approximately equal populations of the isomer with the t-butyl group “axial” and “equatorial.” Analysis of chemical shifts and coupling constants was aided by use of a LAOCOON III program.
"],"dc:identifier":["https://digitalcommons.wku.edu/theses/1425"],"dc:subject":["Chemistry"],"dc:title":["Conformational Analysis of 1-Tertiarybutyl-1, 4-Dihydronaphthalene a Turnover from SRNI to SNI Mechanism"],"dc:type":["Thesis"],"thesis:degree_discipline":["Department of Chemistry"],"thesis:degree_name":["Master of Science"]},"updated_at":"2026-07-24T06:08:39Z"}