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Western Kentucky University

Synthesis of Rhenium and Manganese Pyridazoal Complexes

Abstract

dc:description.abstract

<p>Pyridazines are a heterocyclic aromatic compound containing a characteristic N-N bond that are utilized in many fields, including medicine and electronics. It is this latter field that Dr. Snyder's research group is focused upon. Organometallic compounds are a better conducting material than the current inorganic compounds used in electronics due to better conductance of electricity, lower production cost, and the ability to be formed into thin films. With this in mind, Dr. Snyder's research group has set out to synthesize organometallic compounds for this purpose. Following procedures set forth by Snyder etc, and altered to form an off-metal route, we have successfully synthesized a library of fulvenes, Thalium Cp salts, 5,6 fused pyridazines, and pyridazial complexes. Thalium Cp salts were converted to Rhenium and Magnenese complexes through transmetalation. We have had success with the off-metal route at both higher yields and greater purity than the previous published on-metal route. These compounds have been fully characterized by <sup>1</sup>H NMR, <sup>13</sup>C NMR, IR, and Elemental Analysis. In addition, progress has been initiated to form Bromo Thiophene complexes following procedures set forth in Snyder, etc and modified for the off-metal route. However only fulvenes, pyridazine, and Thalium Cp salts have been synthesized and characterized by <sup>1</sup>H NMR and <sup>13</sup>C NMR.</p>

Degree

thesis:*
Name thesis:degree_name
Master of Science
Discipline thesis:degree_discipline
Department of Chemistry
Year
2013

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Evans, Jesse
Contributors dc:contributor
  • Chad Snyder (Director), Rui Zhang, Rajalingam Dakshinamurthy

Subjects

dc:subject × 11

Identifiers

dc:identifier.*
Repository record dc:identifier
https://digitalcommons.wku.edu/theses/1239
OAI identifier oai:identifier
oai:digitalcommons.wku.edu:theses-2242

Chain of custody

source
Harvested from
Western Kentucky University
Base URL
digitalcommons.wku.edu/do/oai/
Last updated
2026-07-24
Source record
OAI-PMH GetRecord
citation

Evans, Jesse. Synthesis of Rhenium and Manganese Pyridazoal Complexes. 2013. https://digitalcommons.wku.edu/theses/1239