{"id":{"repo_id":"wichita-thes","oai_identifier":"oai:soar.wichita.edu:10057/24967"},"canonical_url":"https://search.dev.ndltd.org/etd/wichita-thes/oai:soar.wichita.edu:10057/24967","repository":{"repo_id":"wichita-thes","name":"Wichita State University","base_url":"https://soar.wichita.edu/oai/request"},"display":{"title":"Synthesis and characterization of polymer nanocomposite materials for advanced application","abstract":"This research attempted to reduce the effect of Corrosion problem in petroleum sector by developing a new series of polymeric inhibitor and polymer nanocomposites coatings. A major aim of these studies was to synthesis a new series of hydroxy ester- amide monomers (N-(2- hydroxypropyl) methacrylamide, 4-((2-hydroxypropyl) amino)-4-oxobutyl methacrylate, 6-((2-hydroxypropyl) amino)-6-oxohexyl methacrylate and 2-((1-hydroxyethyl) carbamoyl) benzyl methacrylate), in addition to a series of ester- amide inimers (1-methacrylamidopropan-2-yl 4-(((butylthio)carbonothioyl)thio)- 4-cyanopentanoate inimer,1-(4-(methacryloyloxy)butanamido) propan-2-yl-4-(((butylthio) carbonothioyl) thio)-4-cyanopentanoate inimer (Butyramide Inimer), 1-(6-(methacryloyloxy) hexanamido)propan-2-yl-4(((butylthio) carbonothioyl) thio)- 4-cyanopentanoate inimer (Capramide Inimer) and 1-(2-((methacryloyloxy)methyl)benzamido) ethyl-4(((butylthio)carbonothioyl)thio)-4-cyanopentanoate inimer (Phthalamide Inimer). Then, the prepared monomers and inimers were polymerized using a controlled/ Living radical polymerization (CRP) by reversible addition fragmentation chain transfer (RAFT) polymerization (CRP-RAFT). The prepared polymers would provide new polymer nano composite coatings for petroleum pipelines based on hydroxy ester-amide type of polymers and graphene oxide material. The morphological characterizations of prepared materials were examined using high resolution transmission electron microscopy (HR-TEM). Polyhydroxy ester-amide linear polymers were used first as a corrosion inhibitor and its composites were used as pigments for anti-corrosive coatings, and the electrochemical investigations, the protection efficiency of the prepared coatings against carbon steel corrosion was studied using electrochemical techniques which are represented asbelectrochemical impedance spectroscopy (EIS) measurements.","abstract_html":"This research attempted to reduce the effect of Corrosion problem in petroleum sector by developing a new series of polymeric inhibitor and polymer nanocomposites coatings. A major aim of these studies was to synthesis a new series of hydroxy ester- amide monomers (N-(2- hydroxypropyl) methacrylamide, 4-((2-hydroxypropyl) amino)-4-oxobutyl methacrylate, 6-((2-hydroxypropyl) amino)-6-oxohexyl methacrylate and 2-((1-hydroxyethyl) carbamoyl) benzyl methacrylate), in addition to a series of ester- amide inimers (1-methacrylamidopropan-2-yl 4-(((butylthio)carbonothioyl)thio)- 4-cyanopentanoate inimer,1-(4-(methacryloyloxy)butanamido) propan-2-yl-4-(((butylthio) carbonothioyl) thio)-4-cyanopentanoate inimer (Butyramide Inimer), 1-(6-(methacryloyloxy) hexanamido)propan-2-yl-4(((butylthio) carbonothioyl) thio)- 4-cyanopentanoate inimer (Capramide Inimer) and 1-(2-((methacryloyloxy)methyl)benzamido) ethyl-4(((butylthio)carbonothioyl)thio)-4-cyanopentanoate inimer (Phthalamide Inimer). Then, the prepared monomers and inimers were polymerized using a controlled/ Living radical polymerization (CRP) by reversible addition fragmentation chain transfer (RAFT) polymerization (CRP-RAFT). The prepared polymers would provide new polymer nano composite coatings for petroleum pipelines based on hydroxy ester-amide type of polymers and graphene oxide material. The morphological characterizations of prepared materials were examined using high resolution transmission electron microscopy (HR-TEM). Polyhydroxy ester-amide linear polymers were used first as a corrosion inhibitor and its composites were used as pigments for anti-corrosive coatings, and the electrochemical investigations, the protection efficiency of the prepared coatings against carbon steel corrosion was studied using electrochemical techniques which are represented asbelectrochemical impedance spectroscopy (EIS) measurements.","abstract_has_math":false,"creators":["Abdelgawad, Ammar M."],"institution":null,"degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2022,"date_issued":"2022-12","date_published":"2022-12","updated_at":"2026-07-24T06:05:36Z","subjects":[],"languages":[],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["hdl:10057/24967"],"render_values":[{"text":"hdl:10057/24967","href":null,"code":true}]}]},"links":{"outbound_url":null,"outbound_label":null,"outbound_source":null},"metadata_groups":[{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.issued","label":"Date","values":["2022-12"]},{"key":"dc:type","label":"Dc Type","values":["Dissertation"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["hdl:10057/24967"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.other","label":"Dc Description Other","values":["This research attempted to reduce the effect of Corrosion problem in petroleum sector by developing a new series of polymeric inhibitor and polymer nanocomposites coatings. A major aim of these studies was to synthesis a new series of hydroxy ester- amide monomers (N-(2- hydroxypropyl) methacrylamide, 4-((2-hydroxypropyl) amino)-4-oxobutyl methacrylate, 6-((2-hydroxypropyl) amino)-6-oxohexyl methacrylate and 2-((1-hydroxyethyl) carbamoyl) benzyl methacrylate), in addition to a series of ester- amide inimers (1-methacrylamidopropan-2-yl 4-(((butylthio)carbonothioyl)thio)- 4-cyanopentanoate inimer,1-(4-(methacryloyloxy)butanamido) propan-2-yl-4-(((butylthio) carbonothioyl) thio)-4-cyanopentanoate inimer (Butyramide Inimer), 1-(6-(methacryloyloxy) hexanamido)propan-2-yl-4(((butylthio) carbonothioyl) thio)- 4-cyanopentanoate inimer (Capramide Inimer) and 1-(2-((methacryloyloxy)methyl)benzamido) ethyl-4(((butylthio)carbonothioyl)thio)-4-cyanopentanoate inimer (Phthalamide Inimer). Then, the prepared monomers and inimers were polymerized using a controlled/ Living radical polymerization (CRP) by reversible addition fragmentation chain transfer (RAFT) polymerization (CRP-RAFT). The prepared polymers would provide new polymer nano composite coatings for petroleum pipelines based on hydroxy ester-amide type of polymers and graphene oxide material. The morphological characterizations of prepared materials were examined using high resolution transmission electron microscopy (HR-TEM). Polyhydroxy ester-amide linear polymers were used first as a corrosion inhibitor and its composites were used as pigments for anti-corrosive coatings, and the electrochemical investigations, the protection efficiency of the prepared coatings against carbon steel corrosion was studied using electrochemical techniques which are represented asbelectrochemical impedance spectroscopy (EIS) measurements."]},{"key":"dc:title","label":"Title","values":["Synthesis and characterization of polymer nanocomposite materials for advanced application"]}]}],"canonical_facts":{"dc:date.issued":["2022-12"],"dc:description.other":["This research attempted to reduce the effect of Corrosion problem in petroleum sector by developing a new series of polymeric inhibitor and polymer nanocomposites coatings. A major aim of these studies was to synthesis a new series of hydroxy ester- amide monomers (N-(2- hydroxypropyl) methacrylamide, 4-((2-hydroxypropyl) amino)-4-oxobutyl methacrylate, 6-((2-hydroxypropyl) amino)-6-oxohexyl methacrylate and 2-((1-hydroxyethyl) carbamoyl) benzyl methacrylate), in addition to a series of ester- amide inimers (1-methacrylamidopropan-2-yl 4-(((butylthio)carbonothioyl)thio)- 4-cyanopentanoate inimer,1-(4-(methacryloyloxy)butanamido) propan-2-yl-4-(((butylthio) carbonothioyl) thio)-4-cyanopentanoate inimer (Butyramide Inimer), 1-(6-(methacryloyloxy) hexanamido)propan-2-yl-4(((butylthio) carbonothioyl) thio)- 4-cyanopentanoate inimer (Capramide Inimer) and 1-(2-((methacryloyloxy)methyl)benzamido) ethyl-4(((butylthio)carbonothioyl)thio)-4-cyanopentanoate inimer (Phthalamide Inimer). Then, the prepared monomers and inimers were polymerized using a controlled/ Living radical polymerization (CRP) by reversible addition fragmentation chain transfer (RAFT) polymerization (CRP-RAFT). The prepared polymers would provide new polymer nano composite coatings for petroleum pipelines based on hydroxy ester-amide type of polymers and graphene oxide material. The morphological characterizations of prepared materials were examined using high resolution transmission electron microscopy (HR-TEM). Polyhydroxy ester-amide linear polymers were used first as a corrosion inhibitor and its composites were used as pigments for anti-corrosive coatings, and the electrochemical investigations, the protection efficiency of the prepared coatings against carbon steel corrosion was studied using electrochemical techniques which are represented asbelectrochemical impedance spectroscopy (EIS) measurements."],"dc:identifier":["hdl:10057/24967"],"dc:title":["Synthesis and characterization of polymer nanocomposite materials for advanced application"],"dc:type":["Dissertation"]},"updated_at":"2026-07-24T06:05:36Z"}